A superhydrophobic surface has many advantages in micro/nanomechanical applications, such as low adhesion, low friction and high restitution coefficient, etc. In this paper, we introduce a novel and simple route to fabricate superhydrophobic surfaces using ZnO nanocrystals. First, tetrapod-like ZnO nanocrystals were prepared via a one-step, direct chemical vapor deposition (CVD) approach. The n...

Photodoped colloidal ZnO nanocrystals are model systems for understanding the generation and physical or chemical properties of excess delocalized charge carriers in semiconductor nanocrystals. Typically, ZnO photodoping is achieved photochemically using ethanol (EtOH) as a sacrificial reductant. Curiously, different studies have reported over an order of magnitude spread in the maximum number ...

The synthesis of ZnO nanocrystals is reported using a hydrothermal chemical growth technique combined with 248 nm nanosecond excimer laser heating at fluences in the range 0 – 390mJ cm. The effect of laser heating in controlling the morphology of the nanocrystals is investigated using optical spectroscopy and electron microscopy characterization. Laser heating is shown to allow control of the c...

ZnO and ZnO:Mn nanocrystals synthesized via reverse micelle method. The size, band gap, Urbach energy, optical constants and penetration depth of nanocrystals were calculated by UV-vis spectroscopy data. The surface morphology was studied with the use of scanning electron microscope (SEM). Moreover the samples exposed to Gama ray source of 60Co and their thermoluminescence properties...

ZnO and ZnO:Mn nanocrystals synthesized via reverse micelle method. The size, band gap, Urbach energy, optical constants and penetration depth of nanocrystals were calculated by UV-vis spectroscopy data. The surface morphology was studied with the use of scanning electron microscope (SEM). Moreover the samples exposed to Gama ray source of 60Co and their thermoluminescence properties...

We theoretically investigate exciton states of colloidal nearly spherical ZnO nanocrystals with diameters from 2 nm to 6 nm. The sizes of considered ZnO nanocrystals are chosen to be slightly larger than the exciton Bohr radius of bulk ZnO. A number of characteristic features of excitons are revealed in this intermediate quantum confinement regime. The exciton center of mass is found to be prol...

Here we demonstrate a single-pot heating approach for controllable synthesis of colloidal zinc oxide nanocrystals from zinc acetylacetonate. Such single-pot heating approaches are inherently amenable to large scale production. We have systematically studied the crystallization process, investigating the growth of nanocrystals and the influence of ligands on the morphology and luminescence of Zn...

Reaction of 3-aminopropylsilyl-modified ZnO microrods with trioctylphosphineoxide-coated CdSe/CdS core/shell nanocrystals in THF produces rod-shaped nanoparticle clusters that show directional photoemission that can be tuned with the size of the CdSe nanocrystals. The observed waveguiding effect of these microstructures is due to total internal reflection of light at the cluster-air interface.

Water-soluble, silane-functionalized ZnO nanocrystals were synthesized with improved colloidal stability, and their photostability was controlled for the selective detection of aldehydes.

Practical, efficient synthesis of metal oxide nanocrystals with good crystallinity and high specific surface area by a modified polymer-network gel method is demonstrated, taking ZnO nanocrystals as an example. A novel stepwise heat treatment yields significant improvement in crystal quality. Such nanophase materials can effectively degrade common organic dyes under solar radiation and can perf...