نتایج جستجو برای: zro2
تعداد نتایج: 3340 فیلتر نتایج به سال:
Although ZrO2 and HfO2 are, for the most part, quite similar chemically, subtle differences in their electronic structures appear to be responsible for differing MO2/Si (M = Zr, Hf) interface stabilities. To shed light on the electronic structure differences between ZrO2 and HfO2, we have conducted joint experimental and theoretical studies. Because molecular electron affinities are a sensitive...
The molecular structures, oxidation states, and reactivity of 3 and 6% CrO3/ZrO2 catalysts prepared by incipient wetness impregnation were examined under different conditions. The in situ Raman spectroscopic studies under dehydrated conditions reveal that the 3 and 6% CrO3/ZrO2 catalysts possess equal amounts of monochromate and polychromate species. Consequently, monolayer coverage on this ZrO...
In Situ FT-IR Spectroscopic Study of CO2 and CO Adsorption on Y2O3, ZrO2, and Yttria-Stabilized ZrO2
In situ FT-IR spectroscopy was exploited to study the adsorption of CO2 and CO on commercially available yttria-stabilized ZrO2 (8 mol % Y, YSZ-8), Y2O3, and ZrO2. All three oxides were pretreated at high temperatures (1173 K) in air, which leads to effective dehydroxylation of pure ZrO2. Both Y2O3 and YSZ-8 show a much higher reactivity toward CO and CO2 adsorption than ZrO2 because of more fa...
Preliminary researches were carried out to study the effects of particle size on the wear behavior of a-C coating. The used nanoparticles are W (W-NPs), which have similar bulk hardness with ZrO2 (W: 7.5, ZrO2: 6.5, Mohs scale), but contain larger particles with the diameter of submicron and micron scale (Figure S1). The tribo-tests were performed under the same conditions with the ones used fo...
Integration of luminescent rare earth ions and iridescence into a zirconium oxide photonic material is attractive for the design of new optical devices. The free-standing chiral nematic mesoporous films of ZrO2:Eu(3+) are assembled by a hard-templating approach using nanocrystalline cellulose-templated silica. The ZrO2:Eu(3+) films show tunable optical properties. The chiral nematic structured ...
In the present investigation, solution casting method was used for the preparation of nanocomposite (NC) films. At first, the surface of ZrO2 nanoparticles (NPs) was modified with vitamin B1 (VB1) as a bioactive coupling agent to achieve a better dispersion and compatibility of NPs within the poly(vinyl chloride) (PVC) matrix. The grafting of modifier on the surface of ZrO2 was confirmed by Fou...
Today, special attention is paid to the use of zirconium dioxide nanoparticle (nano-ZrO2), a neutral bioceramic metal, particularly for drug and gene delivery in medicine. However, there are some reports implying that use of nano-ZrO2 is associated with cytotoxic effects like inhibiting the cell proliferation, DNA damage and apoptosis. In the present study, we examined whether nano-ZrO2 alters ...
In the present study, an investigation into wear properties has been carried out to identify the influence of ZrO2 as the reinforcement material on the LM25 MMC composite. Aluminum LM25 is selected as the base material, and it is reinforced with varying proportions of 0, 3, 6, 9, 12 and 15% of zirconia (ZrO2) manufactured by stir casting. Six tensile test and wear test samples were prepared acc...
Here, we present oxygen-deficient black ZrO2-x as a new material for sunlight absorption with a low band gap around ~1.5 eV, via a controlled magnesiothermic reduction in 5% H2/Ar from white ZrO2, a wide bandgap(~5 eV) semiconductor, usually not considered for solar light absorption. It shows for the first time a dramatic increase in solar light absorbance and significant activity for solar lig...
First principles( or ab initio) density-functional-theory (DFT) with projected augmented wave (PAW) method simulations were performed to calculate the electronic structures and optical properties of 25% nickel (Ni) doped cubic ZrO2 crystals. We implemented two ab initio DFT application methods to the ZrO2 ceramic elastic constant, structure stability, and optical property calculation. The Cerpl...
نمودار تعداد نتایج جستجو در هر سال
با کلیک روی نمودار نتایج را به سال انتشار فیلتر کنید