The synthesis of the ZSM-5 and beta zeolites in their nanosized form has been achieved by using simple alkyl-substituted mono-cationic cyclic ammonium cations as OSDA molecules. The particular combination of a cyclic fragment and a short linear alkyl-chain group (preferentially C4) within the monocationic OSDA molecules allows directing the crystallization of nanosized zeolites with excellent s...

A new kind of organosilane (1,6-bis (diethyl(3-trimethoxysilylpropyl)ammonium) hexane bromide) with a geminitype structure was prepared and used as a mesoporogen for the synthesis of hierarchical porous ZSM-5 zeolite. There are two quaternary ammonium centers along with double hydrolysable -RSi(OMe)3 fragments in the organosilane, which results in a strong interaction between this mesoporogen a...

We report a method to synthesize hollow ZSM-5 single crystals of a size below 100 nm that could function as nanoreactors with access through the zeolite micropores only. In the first step, ZSM-5 is synthesized with the respective crystal size. In the second, the zeolite is base leached and acid washed under mild conditions.

The shape selective catalysis based on ZSM-5 zeolite has found widespread application (1,2) in refining and petrochemical industry since long time. The product distribution associated with hydrocracking and hydroisomerization processes on ZSM-5 are predominantly controlled by the pore geometry and component diffusion. The various aspects of diffusion inside ZSM-5 pore structure have been widely...

The most studied catalysts for methane dehydroaromatization (MDA)?Mo/ZSM-5?are not commercialized yet due to the rapid deactivation and insufficient activity. Catalytic systems based on Fe Re are potential alternatives Mo-containing zeolites. Here, we compare catalytic performance of these as a function metal type its loading in ZSM-5 zeolite. results show that activity decreases order Re/ZSM-5...

The catalytic activity of large zeolite H-ZSM-5 crystals in methanol (MTO) and ethanol-to-olefins (ETO) conversions was investigated and, using operando UV/Vis measurements, the catalytic activity and deactivation was correlated with the formation of coke. These findings were related to in situ single crystal UV/Vis and confocal fluorescence micro-spectroscopy, allowing the observation of the s...

Herein we report FTIR in situ adsorption of molecular hydrogen, carbon monoxide, water, methanol, pyridine and 2,4,6-trimethylpyridine (collidine) on nanosheet H-ZSM-5 which was recently studied in the methanol to hydrocarbons (MTH) reaction. The nature of the hydroxyl groups and surface species are described in detail. The IR spectrum of nanosheet H-ZSM-5 is dominated by silanols, which satura...