Quinolactacide isolated from Penicillium citrinum F 1539 was synthesized and evaluated for its insecticidal activities. The key steps of the total synthesis were an acyl migration reaction of the enol ester intermediate and dehydrogenation of tetrahydroquinolactacide with manganese dioxide. The synthesized quinolactacide showed 100% and 42% mortality against the green peach aphid (Myzus persica...

A new, cost-effective, and environmental-friendly cloud point extraction methodology was described for enrichment of copper, manganese and nickel in several water samples. The method involves the complexation of copper, manganese or nickel with 2-amino-6-(1,3-thiazol-2-diazeyl)-phenol at pH 7.0, then extraction into Triton X-114. After dilution of the surfactant-rich phase with acidified methan...

To clarify whether manganese nutritional status is better reflected by the manganese concentration in lymphocytes or in whole blood, we injected manganese solutions intravenously into manganese-deficient rats and determined manganese concentrations in lymphocytes, whole blood, and various tissues. The manganese concentrations in lymphocytes and tissues, but not in whole blood, were significantl...

Nowadays, lithium-ion batteries (LIBs) are one of the most convenient, reliable, and promising power sources for portable electronics, tools, hybrid electric vehicles. The characteristics positive electrode (cathode active material, CAM) significantly contribute to battery’s functional properties. Applying various coatings is productive ways improve work batteries. there many methods depositing...

UNLABELLED Manganese plays an important role in the cellular physiology and metabolism of bacterial species, including the human pathogen Vibrio cholerae The intracellular level of manganese ions is controlled through coordinated regulation of the import and export of this element. We have identified a putative manganese exporter (VC0022), named mneA (manganese exporter A), which is highly cons...

Magnetic resonance studies of the activation of arginase (L-arginine amidinohydrolase, EC 3.5.3.1) with manganese have been performed with nuclear magnetic resonance. The results showed that 4 moles of manganese were bound per mole of fully activated arginase. However, the binding affinities of the metal ions to the enzyme were not identical; 50% of the MnZ+ was strongly bound and could not be ...

Manganese (Mn)-induced neurotoxicity can occur due to environmental exposure (air pollution, soil, water) and/or metabolic aberrations (decreased biliary excretion). High brain manganese levels lead to oxidative stress, as well as alterations in neurotransmitter metabolism with concurrent neurobehavioral deficits. Based on the few existing studies that have examined brain regional Mn concentrat...

Escherichia coli does not routinely import manganese, but it will do so when iron is unavailable, so that manganese can substitute for iron as an enzyme cofactor. When intracellular manganese levels are low, the cell induces the MntH manganese importer plus MntS, a small protein of unknown function; when manganese levels are high, the cell induces the MntP manganese exporter and reduces express...

In situ X-ray absorption spectroscopy (XAS) is a powerful technique that can be applied to electrochemical systems, with the ability to elucidate the chemical nature of electrocatalysts under reaction conditions. In this study, we perform in situ XAS measurements on a bifunctional manganese oxide (MnOx) catalyst with high electrochemical activity for the oxygen reduction reaction (ORR) and the ...