An amplified impedimetric aptasensor combining target-induce DNA Hydrogel formation with pH-stimulated signal amplification for heparanase assay Zhe-Han Yang, Ying Zhuo, Ruo Yuan*, Ya-Qin Chai* Key Laboratory of Luminescent and Real-Time Analytical Chemistry (Southwest University), Ministry of Education, College of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, PR C...

The chemical oxidation polymerization of m-phenylenediamine (MPD) by ammonium persulfate (APS) at room temperature results in the formation of poly(m-phenylenediamine) (PMPD) microparticles. The subsequent treatment of such microparticles with an aqueous AgNO(3) solution produces Ag nanoparticle (AgNP)-decorated PMPD microparticles. It was found that as-formed AgNPs exhibited remarkable catalyt...

In order to modify the xanthan gum (XG) polysaccharide and to develop the hydrogels meant for the drug delivery, we have prepared XG-g-poly [HEMA-co-AA] superporous hydrogel (SPH) through chemical cross-linking by graft copolymerization of 2-hydroxyethyl methacrylate (HEMA) and acrylic acid (AA) on to XG via redox initiator system of ammonium persulfate (APS) and N, N, N’, N’tetramethylethylene...

Heat-activated persulfate was tested for destruction of polychlorinated dibenzo-p-dioxins/furans (PCDD/Fs) in the laboratory. Combined technology of in situ chemical oxidation (ISCO) and in situ thermal remediation (ISTR) using heat-activated persulfate can be applied for destruction of the PCDD/Fs polluted soil and the PCDD/Fs containing fly ash from incineration process. To explore the treata...

Activated persulfate oxidation technologies based on sulfate radicals were first evaluated for defluorination of aqueous perfluorooctanesulfonate (PFOS). The influences of catalytic method, time, pH and K2S2O8 amounts on PFOS defluorination were investigated. The intermediate products during PFOS defluorination were detected by using LC/MS/MS. The results showed that the S2O8 (2-) had weak effe...

Occupational allergic contact eczema and asthma caused by bleaching agents is seen in hairdressers. Bleaching agents contain persulfate salts, which are known to induce immediate reactions such as rhinitis, asthma, contact urticaria, and anaphylaxis. The immunologic mechanism is not, however, fully understood. The specific inhalation challenge test is considered to be the gold standard for diag...

An alternative approach toward understanding and advancing hydrogel-based single walled carbon nanotube (SWNT) purification is described employed. Experimental atomistic modeling analysis of the leading hydrogel for SWNT purification, Sephacryl S200, affords creation gels that mimic its behavior in terms dependent interaction properties. This achievement introduces a generalized optimization me...