Metal-organic frameworks (MOFs) provide access to structures with nanoscale pores, the size and connectivity of which can be controlled by combining the appropriate metals and linkers. To date, there have been no reports of using MOFs as templates to make porous, crystalline metal oxides. Microporous titania replicas were made from the MOF template HKUST-1 by dehydration, infiltration with tita...

TiO2 nanopowder is prepared by simple sol-gel method using starting material as titanium isopropoxide with methanol and annealed at 600°C, 700°C and 800°C for 1 hour in air. X-ray diffraction pattern revealed the presence of both anatase and rutile phase in TiO2 specimens annealed at different temperatures. It is observed that the content of rutile phase and crystallite size increases with incr...

A number of mono(carboxylato )mono(a lkoxo)nicke l ( I I ) complexes of the general formula, N i ( O R ) ( O O C R ' ) , (with R ' = C13H07, C15H31 and C17H35) have been synthesized (where R = Me and Pr») b y the reactions o f nickel methoxide and isopropoxide with the respective carboxyl ic acids in equimolar ratio and (where R = E t and Bu<) by alcohol interchange reactions. A study of the mo...

YAG:Ce3+ nanoparticles 9.5+/-1.2 nm in diameter have been synthesized from aluminium isopropoxide and acetates of yttrium and cerium in 1,4-butanediol (1,4-BD) by autoclave treatment at 300 degrees C for 2 h. After replacing 1,4-BD by ultrapure water, NH2 groups were introduced on the surface of YAG:Ce3+ nanoparticles by addition of 3-aminopropyltrimethoxysilane then biotinylation with sulfo-NH...

In this study PbTiO 3 thin films were deposited using metalorganic vapor phase epitaxy (MOVPE). Titanium-isopropoxide and tetraethyl-lead were used as the Ti and Pb precursors, and 0 2 was the oxidizing gas. A wide range of conditions for preparing high quality PbTiO 3 thin film were investigated. The epitaxial PbTiO 3 thin films were grown on (001) SrTiO 3 substrates at a growth temperature of...

The objective of the present study was to determine the number of active surface sites and their nature, redox or acidic, for bulk metal oxide catalysts using isopropanol as a chemical probe molecule. Isopropanol oxidation activity on the following metal oxides was investigated: MgO, CaO, SrO, BaO, Y2O3, La2O3, CeO2, TiO2, ZrO2, HfO2, V2O5, Nb2O5, Ta2O5, Cr2O3, MoO3, WO3, Mn2O3, Fe2O3, Co3O4, R...

Electrodeposited aluminum films and template-synthesized aluminum nanorods are examined as negative electrodes for lithium-ion batteries. The lithium-aluminum alloying reaction is observed electrochemically with cyclic voltammetry and galvanostatic cycling in lithium half-cells. The electrodeposition reaction is shown to have high faradaic efficiency, and electrodeposited aluminum films reach t...