The title compound, [Cu(NH3)4-(μ2-NC)-Pd(CN)3], is a binuclear copper(II)palladium(II) complex, in which the Cu(II) coordination is defined by four ammine ligands and one bridging cyanide ligand. The Cu-N bond lengths in the base of the resulting CuN5 pyramid are in the range 2.016 (3)-2.024 (3) Å and the apical Cu-N( C) distance is 2.385 (4) Å. Based on the τ parameter, the shape of the coordi...

The reaction of cis-[Pt(NO(3))(2)(NH(3))(2)] and sodium glycolate yielded the title compound, [Pt(C(2)H(2)O(3))(NH(3))(2)]. The Pt(II) atom, coordinated by two N atoms of ammine and two O atoms of the carboxyl-ate and oxido groups of the glycolate ligand, is in a square-planar environment. In the crystal structure, mol-ecules are connected by inter-molecular N-H⋯O hydrogen bonds, forming a thre...

Cu-Mn alloy films are electrodeposited on Au substrates as precursor alloys for the synthesis of fine-structured nanoporous Cu structures. The deposited galvanostatically in a solution containing ammonium sulfate, (NH4)2SO4, which serves source ammine ligand that complexes with Cu, thereby decreasing inherent standard reduction potential difference between and Mn. formation [Cu(NH3)n]2+ complex...

A semi-quantitative method is presented for predicting the transition structure bond length and the kinetic energy released as a diatomic dication dissociates into monocation fragments. Our approach, which we term the ACDCP model, involves the introduction of diabatic coupling and polarization effects to an avoided-crossing model previously described. Good agreement is found between the predict...