A Ni(II) porphyrin functionalized with an alkyl carboxylic acid (3) has been synthesized to model the chemical behavior of the heaviest portion of petroleum, the asphaltenes. Specifically, porphyrin 3 is used in spectroscopic studies to probe aggregation with a second asphaltene model compound containing basic nitrogen (4), designed to mimic asphaltene behavior. NMR spectroscopy documents self-...

X-ray Raman spectra of the carbon K-edge have been recorded using 6.461 keV radiation for a petroleum asphaltene. By comparison with coronene, graphite, and paraffin standards, the asphaltene spectrum is seen to be composed of contributions from saturated and aromatic carbon species. The information contained in the carbon K-edge was extracted with bulk (approximately 1 mm) sensitivity, because...

Water-in-crude oil emulsions are formed during petroleum production and asphaltenes play an important role in their stabilization. Demulsifiers are added to destabilize such emulsions,however the demulsification mechanism is not completely known. In this paper, the performances of commercial poly(ethylene oxide-b-propylene oxide) demulsifiers were studied using synthetic water-in-oil emulsions ...

Seven crude oil samples recovered from wells of El Hamd and Bakr oil Fields locates in Egyptian central Gulf of Suez were subjected for Description, bulk composition of Maltene Fraction and hydrocarbons distribution. The Comparison of collected crude oils was achieved using Bulk parameters and Specific parameters, the first ones refer to properties of the whole sample such as API gravity, sulfu...

asphaltenes are the n-pentane or n-heptane insoluble fractions of crude oil that remain in solution under reservoir temperature and pressure conditions. they are destabilized and start to precipitate when the pressure, temperature and/or composition changes occur during primary production. the precipitated asphaltene particles will then grow in size and may start to deposit onto the production ...

Effects of different flocculants (chloride-based salts and ferric and ferrous salts) and initial organic concentration of wastewater on flocculation-photocatalysis hybrid process were investigated. Titanium Dioxide (TiO2) adsorption alone, flocculation alone, flocculation followed by TiO2 adsorption, photocatalysis alone, and flocculation followed by photocatalysis removed 60%, 72%, 80%, 85%, a...

in this work the likelihood of asphaltene deposition problems during dynamic displacement of oil by natural gas in unconsolidated porous media is experimentally inspected. the two different rock materials, limestone and sandstone, are used as a representative of porous media. dynamic flow experiments indicate that the increase of natural gas injection increases asphaltene deposition in the unco...

Flocculation is one of the principal steps in biodiesel production from microalgae. Eight different flocculants were analysed for their efficiency of flocculation of marine microalga, Nannochloropsis oculata. Maximum flocculation was observed as 93.80 and 87.33% with FeCl3 and Fe2(SO4)3 at a concentration of 0.4 and 0.6g/L respectively at 180min. Zinc salts achieved second maximum efficient flo...

Asphaltenes are the n-pentane or n-heptane insoluble fractions of crude oil that remain in solution under reservoir temperature and pressure conditions. They are destabilized and start to precipitate when the pressure, temperature and/or composition changes occur during primary production. The precipitated asphaltene particles will then grow in size and may start to deposit onto the product...

one of the most paramount processes that play a considerable role in reducing the concentration of heavy metals during estuarine mixing is flocculation. not only does such a process cause a huge percentage of metals to come into the particulate phase, but also it provides ample nutrients for the aquatic life. in the present study, impact of such factors as salinity, ph and do on flocculation of...