A high-performance liquid chromatography with ultraviolet detection (HPLC/UV) methodwhich was used solid-phase extraction for cleanup, was developed for the determination ofAzinphos methyl ,Phosalone, Diazinon and Chlorpyrifos residues in fruits. A full factorialexperimental design was used for development of HPLC condition and evaluation of effect ofthree factors (pH of mobile phase, percent o...

Guthion, a trade name for azinphos-methyl, is a restricted use organophosphate insecticide that is primarily used as a foliar application against phytophagous insect pests on fruit, field, or vegetable crops and works as both a contact insecticide and a stomach poison. In 2002, the estimated annual agricultural use of guthion had declined to about 1.2 million pounds, nearly a 50% decline from 1...

Analysis of pollen trapped from honey bees as they return to their hives provides a method of monitoring fluctuations in one route of pesticide exposure over location and time. We collected pollen from apiaries in five locations in Connecticut, including urban, rural, and mixed agricultural sites, for periods from two to five years. Pollen was analyzed for pesticide residues using a standard ex...

Two multiresidue methods were developed to determine pesticides in air collected in California. Pesticides were trapped using XAD-4 resin and extracted with ethyl acetate. Based on an analytical method from the University of California Davis Trace Analytical Laboratory, pesticides were detected by analyzing the extract by gas chromatography-mass spectrometry (GC-MS) to determine chlorothalonil,...

Spraydrift and edge-of-field runoff are important routes of pesticide entry into streams. Pesticide contamination originating from spraydrift usually resides in the water phase, while pesticides in contaminated runoff are to a large extent associated with suspended particles (SPs). The effects of two organophosphorous insecticides (OPs), chloropyrifos (CPF) and azinphos-methyl (AZP), on acetylc...

Codling moth, Cydia pomonella (L.), remains a principal insect pest of tree fruit orchards throughout the temperate regions of the world (Barnes 1991; Beers et al. 1993). Its larvae bore deep into the fruits of apple, pear and walnut making them unmarketable. The majority of conventional growers still rely on chemical insecticides to control this insect. However, concerns regarding development ...

Drift from pesticide spray application can result in contamination of nontarget environments such as surface waters. Azinphos-methyl (AZI) and endosulfan (END) deposition in containers of water was studied in fruit orchards in the Western Cape, South Africa. Additionally, attention was given to the contamination in farm streams, as well as to the resulting contamination of the subsequent main c...

We measured two diethyl organophosphorus (OP) pesticides--chlorpyrifos and parathion--in residences, and their metabolic by-products, in the urine of children 6 years old or younger in a central Washington State agricultural community. Exposures to two dimethyl OP pesticides (azinphos-methyl and phosmet) in this same population have been reported previously. We categorized children by parental ...

Sulprofos, disulfoton, azinphos-methyl, methamidophos, trichlorfon, and tebupirimphos were screened for neurotoxic potential, in accordance with U.S. EPA (FIFRA) requirements. Each organophosphate was administered through the diet for 13 weeks to separate groups of Fischer 344 rats at four dose levels, including a vehicle control. For each study, 12 rats/sex/dietary level were tested using a fu...

BACKGROUND Exposure to organophosphate (OP) pesticides is an occupational hazard for farmworkers and affects their children through the take-home pathway. OBJECTIVES We examined the effectiveness of a randomized community intervention to reduce pesticide exposure among farmworkers and their children. METHODS We conducted a baseline survey of a cross-sectional sample of farmworkers (year 1) ...