Introduction Azo dyes – a fatal threat or a new generation of drugs? In 1858 Griss developed the azo coupling reaction and obtained first azo dye – Aniline Yellow. Nowadays, around 10 thousands of these compounds are described and more than 2 thousands are applied to color various materials. Azo dyes are characterized by the presence of the azo moiety (–N=N–) in their structure, conjugated with...

Approximately 0.7 million tons of azo dyes are synthesized each year. Azo dyes are composed of one or more R₁-N=N-R₂ linkages. Studies have shown that both mammalian and microbial azoreductases cleave the azo bonds of the dyes to form compounds that are potentially genotoxic. The human gastrointestinal tract harbors a diverse microbiota comprised of at least several thousand species. Both water...

2-Amino-1,3-benzothiazole was synthesized and schiff bases were prepared by reacting a series of aromatic aldehydes with 2-amino-1,3-benzothiazole to form a number of potentially biologically active compounds. Azo dyes of 2-amino-1,3-benzothiazole were synthesized by reacting various aromatic amines , substituted amines and phenols. The structures of 2-amino-1,3-benzothiazole, Schiff bases and ...

Azo dye decolourisation can be easily achieved by biological reduction under anaerobic conditions. The aim of this study was to evaluate the applicability of submerged anaerobic membrane bioreactors (SAMBRs) for the decolourisation of dyeing wastewater containing azo dyes. The reactive orange 16 was used as model of an azo dye. The results demonstrated that very high decolourisation (higher tha...

We present a novel approach to reversibly control the assembly of liposomes through an anchored multistimuli responsive DNA oligonucleotide decorated with an azobenzene moiety (AZO-ON1). We show that liposomes assembly can be simultaneously controlled by three external stimuli: light, Mg(2+), and temperature. (i) Light alters the interaction of AZO-ON1 with liposomes, which influences DNA coati...

Global environmental pollutants are becoming intense because of the increasing human population, urbanisation, and industrialisation. Human health ecosystem affected by soil water contamination. Therefore, creating strategies is essential to tackle this persistent issue. In process, risk associated with these can be signifi-cantly reduced. Previously, traditional remediation techniques have bee...

In this study PbZrO3 was prepared as a matrix by the sol-gel process and is characterized by XRD and SEM techniques. The particle size of the synthesized nanocomposite is evaluated about 43 nm. The Lead Zirconate is then doped with Ce3+/TiO2 in different ratios. Nanocomposites are added in the reaction in a photoreactor with a pollutant (an Azo dye) and as a result the degradation percentage is...

Azo dyes are synthetic organic used in the textile, leather, and paper industries. They pose environmental problems due to their toxic persistent nature. The toxicity is presence of azo groups dye molecule that can break down into aromatic amines, which highly aquatic organisms humans. Various treatment methods have been developed remove from wastewater. Conventional wastewater treatments some ...

Azo-functionalized MOPs (Azo-MOPs) were synthesized via oxidative polymerization of aromatic amines catalyzed by t-BuOCl/NaI (25 °C, 1 h, yield: >95%), which displayed an excellent coordinating ability with a Ru complex. The resulting Ru-coordinated Azo-MOPs displayed high CO2 capacity and high performances for catalyzing the methylation of amines with CO2 under low pressure (0.5 MPa).

Transparent conductive aluminum-doped ZnO (AZO) films were prepared by RF magnetron sputtering on glass substrates with specifically designed ZnO target using high-purity of zinc oxide (99.99%) and aluminum hydroxide (99.99%) powders. Systematic study on dependence of target-to-substrate distance (D ) on structural, electrical and optical properties of the as-grown AZO ts films was mainly inves...