Abstract The in situ X-ray photoelectron spectroscopy data indicate that butyltrimethylammonium bis(trifluoromethylsulfonyl)imide (N4111(TFSI)) adsorbs strongly within the potential range −3.25 V < E −2.25 and specifically at (vs. Ag-QRE) Al electrode. Strong adsorption of intermediates N4111(TFSI) electrochemical decomposition was observed impedance cyclic voltammetry measurements. At −4.25...

Abstract Upscaling of nanoparticle fabrication by sputtering into an ionic liquid is shown for the example Cu. Long-time (24 h) a large amount (50 mL) 1-butyl-3-methylimidazolium bis-(trifluoromethylsulfonyl)imide [Bmim][(Tf) 2 N] yields approximately 1 g Cu nanoparticles (mean spherical diameter (2.6 ± 1.1) nm), stabilized in without agglomerations. Extraction from stabilizing was performed wi...

Abstract The in situ X-ray photoelectron spectroscopy data indicate that butyltrimethylammonium bis(trifluoromethylsulfonyl)imide (N4111(TFSI)) adsorbs strongly within the potential range ?3.25 V < E ?2.25 and specifically at (vs. Ag-QRE) Al electrode. Strong adsorption of intermediates N4111(TFSI) electrochemical decomposition was observed impedance cyclic voltammetry measurements. At ?4.25...

Gel polymer electrolytes (GPEs) are developed using poly(1-vinylpyrrolidone-co-vinyl acetate) [P(VP-co-VAc)] as the host polymer, lithium bis(trifluoromethane) sulfonimide [LiTFSI] as the lithium salt and ionic liquid, and 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide [EMImTFSI] by using solution casting technique. The effect of ionic liquid on ionic conductivity is studied and...

Despite the availability of a large number of alkyl tetrahydrofurfuryl ethers that have a wide range of applications, pure bis(tetrahydrofurfuryl) ether (BTHFE) has not been previously synthesized. Here, we report the synthesis of BTHFE (consisting of the RR, SS, and meso stereoisomers) at greater than 99 % purity from tetrahydrofurfuryl alcohol, using (tetrahydrofuran-2-yl)methyl methanesulfon...