The present paper describes the orientational control of 10 nm scale cylinders in sugar-based block copolymer thin films by simply varying the composition of the annealing co-solvent. The affinity of the block copolymer to the solvent vapor could be systematically adjusted in this way.

In this study, poly carbonate (PC) and poly (ethylene terephthalate) (PET) were reactive melt-blended under two different conditions to produce PC/PET copolymers. For each condition, samples were taken at specified mixing times representative a specific structure of copolymers and each one employed to physically compatibilize a PC/PET blend with a fixed composition. Reactive blending and copoly...