Cellulose sulfuric acid was used as an efficient biopolymer-based catalyst for the synthesis of tetrahydropyrimido[4,5-b]quinoline-2,4,6-triones and hexahydro-2H-pyrazolo[5,4-b]quinoline-6-ones via three component reaction of aldehyde, 5,5-dimethyl-1,3-cyclohexadione and 6-amino-1,3-dimethyluracil or 5-amino-3-methyl-1-phenypyrazole under solvent-free conditions at 90 oC. The major advantages o...

Cellulose sulfuric acid was used as an efficient biopolymer-based catalyst for the synthesis of tetrahydropyrimido[4,5-b]quinoline-2,4,6-triones and hexahydro-2H-pyrazolo[5,4-b]quinoline-6-ones via three component reaction of aldehyde, 5,5-dimethyl-1,3-cyclohexadione and 6-amino-1,3-dimethyluracil or 5-amino-3-methyl-1-phenypyrazole under solvent-free conditions at 90 oC. The major advantages o...

Acid hydrolysis treatment of kenaf outer bast fiber can produce pure cellulose content and hydrolyzed hemicellulose to monosaccharides. The effects various reaction temperatures (110–130 °C), acid concentrations sulfuric (0.25–1.00 N), times (60–120 min) were investigated as the optimum condition gain content. A 1H NMR spectroscopy was used analyze carbohydrate in treatment. results showed that...

cellulose sulfuric acid was used as an efficient biopolymer-based catalyst for the synthesis of tetrahydropyrimido[4,5-b]quinoline-2,4,6-triones and hexahydro-2h-pyrazolo[5,4-b]quinoline-6-ones via three component reaction of aldehyde, 5,5-dimethyl-1,3-cyclohexadione and 6-amino-1,3-dimethyluracil or 5-amino-3-methyl-1-phenypyrazole under solvent-free conditions at 90 oc. the major advantages o...

In this work, a sustainable and green process to prepare nanocrystalline cellulose (NCC) from bleached hardwood pulp was demonstrated. Rod-like nanocrystalline cellulose with the size of 15-40 nm in width and hundreds of nanometers in length was obtained through H3PW12O40 (HPW)-catalyzed hydrolysis of bleached pulp fibers under the mild reaction conditions. Thermogravimetric analysis revealed t...

Technologies to collect and reuse sulfuric acid waste is attracting attention to reduce industrial waste in semiconductor manufacturing plants. Reusing sulfuric acid has a high economic value. By using sulfuric acid recycling equipment based on an atmospheric distillation method, we evaluated the recovery percentage of sulfuric acid, the concentration and quality of recycled sulfuric acid, and ...

Cellulosic biomass can be pretreated with dilute sulfuric acid to recover high yields of sugars directly from hemicellulose and subsequently by enzymatic hydrolysis of the residual cellulose, and these sugars can be used to produce fuels and chemicals with unique and powerful economic, environmental, and strategic benefits. Pretreatment is costly for such biological routes, and we seek to bette...

This research investigated the ability of on-farm pretreatments with acid, alkali, ozone or novel enzymes to improve enzymatic degradability of cellulose and hemicelluloses in biomass at the biorefinery. Two perennial grasses, switchgrass (Panicum virgatum) and reed canarygrass (Phalaris arundinacea L.), were direct-cut harvested, pretreated, and stored anaerobically for 30 d. Pretreated and un...