A novel asymmetric zinc (II) phthalocyanine substituted by one lipophilic octadecyloxyl group and three hydrophilic glucosyl groups was synthesized. Using Q-TOF MS, the major byproducts formed during the deprotection processes were identified. An improved procedure was worked out to convert these byproducts to the desired product in quantitative yield.

The meta-analysis of plant sterol supplement studies suggests an 8% lowering of low density lipoprotein (LDL) cholesterol for 2 to 2.5 g/day of plant sterols. Cereal foods have been rarely tested, and one study showed a lower LDL lowering of 5.4% with 1.6 g of plant sterol in breakfast cereal. We aimed to test a breakfast wheat biscuit with 2 g of plant sterols in a single serve of two wholegra...

Iron deficiency (ID) affects 13.5% of 1-2 years old children in the US and may have a negative impact on neurodevelopment and behavior. Iron-fortified infant cereal is the primary non-heme iron source among infants aged 6-11.9 months. The objective of this study was to compare iron intakes of infant cereal users with non-users. Data from the Feeding Infants and Toddlers Study 2008 were used for...

Cereal products exhibit a wide range of glycaemic indexes (GI), but the interaction of their different nutrients and starch digestibility on blood glucose response is not well known. The objective of this analysis was to evaluate how cereal product characteristics can contribute to GI and insulinaemic index and to the parameters describing glycaemic or insulinaemic responses (incremental AUC, m...

virtual water adds a new dimension to crop trades and provides a new way of thinking about water scarcity. a systematic analysis of virtual water flows requires integration of all critical drivers of virtual water flows under a single consistent framework. the aim of this study was to assess virtual water flows related to trades of grain crops (wheat, corn, rice, and coarse cereals) and their i...

Yearling and calf finishing trials (replicated over 2 yr) evaluated the feeding value of wet distillers byproducts (wet distillers grains and thin stillage). An additional trial estimated the amount of thin stillage bypassing the rumen when consumed by drinking. Yearlings were 5, 10, and 20% more efficient (linear, P < .01; quadratic, P = .05), whereas calves were 2, 6, and 14% more efficient (...

OBJECTIVES To estimate the intakes of cereal and dairy products and their contribution to nutrient intakes in men and women from the Republic of Ireland with a view to formulating food-based dietary guidelines. DESIGN The North/South Ireland Food Consumption Survey established a database of habitual food and drink consumption using a 7-day food diary. From this database all cereal and dairy p...

Arabinoxylans are considered as the major limiting factor for use of rye in animal feeding. In this study, four selected winter rye cultivars were grown at nine locations and tested for arabinoxylans including total (TAX), soluble (SAX) and insoluble fractions (IAX), extract viscosity, falling numbers and crude protein contents. Amounts of TAX ranged on average between 89 and 103 g/kg wholemeal...