CONTEXT The terrestrial planets, comets, and meteorites are significantly enriched in 15N compared to the Sun and Jupiter. While the solar and jovian nitrogen isotope ratio is believed to represent the composition of the protosolar nebula, a still unidentified process has caused 15N-enrichment in the solids. Several mechanisms have been proposed to explain the variations, including chemical fra...

Grape seed oil is a product resulting from the processing of grape marc. It is ever more appealing for the cosmetic and pharmaceutical industries: the pharmaceutical activities concern its antioxidant properties, due to the large content of unsaturated fatty acids. Grape seed oil could be extracted mechanically by pressing or chemically by means of solvents. Among the latter, supercritical CO2 ...

The vast majority of commercial polyolefins are semi-crystalline materials. Depending on the chemical composition and tacticity, their melting temperatures range from ambient to temperatures exceeding 160 C. Polyolefins form various crystalline structures that can be investigated with microscopic, spectroscopic and scattering techniques. When a semi-crystalline polyolefin is dissolved in a solv...

We present a method to determine (88)Sr/(86)Sr and (87)Sr/(86)Sr simultaneously. The former variation reflects the mass-dependent isotopic fractionation through the physico-chemical processes, and the latter originates from beta(-)-decay of the parent nuclide (87)Rb as well as the mass-dependent isotopic fractionation. In order to determine the mass-dependent isotopic fractionation, the mass-di...

Deuterium isotope effects and fractionation factors of N1.H3-N3 hydrogen bonded Watson-Crick A:T base pairs of two DNA dodecamers are presented here. Specifically, two-bond deuterium isotope effects on the chemical shifts of (13)C2 and (13)C4, (2)delta(13)C2 and (2)delta(13)C4, and equilibrium deuterium/protium fractionation factors of H3, Phi, were measured and seen to correlate with the chemi...

A study of the chemical structure of the envelopes around a sample protostars is introduced. Physical models for the envelopes derived using 1D radiative transfer modeling of their dust continuum emission are used as input for Monte Carlo modeling of single-dish line observations in order to establish the chemical inventories for the different sources. CO and HCO abundances are found to be corr...

A comparative study among different pretreatment methods used for the fractionation of the birch outer bark components, including steam explosion, hydrothermal and organosolv treatments based on the use of ethanol/water media, is reported. The residual solid fractions have been characterized by ATR-FTIR, (13)C-solid-state NMR and morphological alterations after pretreatment were detected by sca...

Context Abstract: N2O has been identi®ed in the Kyoto Protocol as one of the six greenhouse gases for which anthropogenic emissions should be regulated, however, regulation procedures may not be implemented until a wellde®ned N2O budget has been established. The measurement of N2O isotopic fractionation provides a potential means for constraining the global budget since biological and anthropog...