The preparation and spectroscopic characterization of a CO-inhibited [FeFe] hydrogenase with a selectively (57)Fe-labeled binuclear subsite is described. The precursor [(57)Fe2(adt)(CN)2(CO)4](2-) was synthesized from the (57)Fe metal, S8, CO, (NEt4)CN, NH4Cl, and CH2O. (Et4N)2[(57)Fe2(adt)(CN)2(CO)4] was then used for the maturation of the [FeFe] hydrogenase HydA1 from Chlamydomonas reinhardti...

The non-sulfided Ni-PTA/Al2O3 catalyst was developed to produce green diesel from the hydroprocessing of Jatropha oil. The Ni-PTA/Al2O3 catalyst was prepared by one-pot synthesis of Ni/Al2O3 with the co-precipitation method and then impregnanting Ni/Al2O3 with PTA solution. The catalysts were characterized with BET, SEM-EDX, TEM, XRD, XPS, TGA and NH3-TPD. The Ni and W species of the Ni-PTA/Al2...

The catalytic properties of LaCoO3 in aqueous oxidation are explored as a function of doping. Both Sr substitution for La and Fe/Ni substitution for Co are studied. The reaction of interest is the aqueous epoxidation of crotyl alcohol with hydrogen peroxide. The reaction products are measured using GC, and the decomposition of hydrogen peroxide is studied using the volume of oxygen evolved duri...

In this study, we used quantum mechanics (QM) to investigate steam reforming of methane on Ni-alloy catalyst surfaces and to examine the effect of anode material modifications on the catalytic processes in a solid oxide fuel cell (SOFC). The conventional Ni anode suffers from coking, coarsening, and sulfur poisoning because of the decomposition of hydrocarbon fuels, Ni particle agglomeration at...

The divalent transition-metal cations Fe, Co, and Ni were used to test the hypothesis that Mn ions pass through calcium channels because Mn ions have a relatively low energy of hydration. The test ions were applied to the bath and comparisons were made of their effects on Ca or Mn spikes elicited from myoepithelial cells of the proventriculus of the polychaete worm Syllis spongiphila. Control e...

The reaction of Fe(CO)(2)(NO)(2) and Ni(N(2)S(2)) (N(2)S(2) = N,N'-Bis(2-mercaptoethyl)-1,4-diazacycloheptane) by a single CO replacement yields [Ni(N(2)S(2))]Fe(NO)(2)(CO), while an excess of Fe(CO)(2)(NO)(2) leads to triply bridging thiolate sulphurs in a cluster of core composition Ni(2)S(4)Fe(3), lacking one Fe(NO)(2) unit to complete the adamantane-like structure. This structural type was ...

Nanowire is a cylindrical nano-structure with nanometer dimensions. In this research, the studied nanowire was made from the magnetic triple Ni-Fe-Co alloy.&#10 We utilized ordered porous anodic aluminum oxide as a template for the nanowire deposition. The nanowire arrays were electrodeposited in the cylindrical pores of the oxide layer by AC potential in a simple sulfate bath. Then the relatio...

Effects of ultra high magnetic field of both pulse and steady types on martensitic transformation have been studied, using Fe-Ni-Mn, Fe-Ni-Mn-C alloys with the supplemental tests on Fe-Ni-C and Fe-NiCo-Ti alloys. It is found that the martensitic transformation is induced at room temperature not only athermally but also isothermally either by pulse magnetic field or by steady magnetic field for ...

Our group recently reproduced the water-assisted growth method, so-called "SuperGrowth", of millimeter-thick single-walled carbon nanotube (SWNT) forests by using C2H4/H2/H2O/Ar reactant gas and Fe/Al2O3, catalyst. In this current work, a parametric study was carried out on both reaction and catalyst conditions. Results revealed that a thin Fe catalyst layer (about 0.5 nm) yielded rapid growth ...

Despite our extremely low atmospheric concentration of dihydrogen (B1 ppm), this substrate is a key metabolite of many anaerobic bacteria. In such living systems can be found the most prevalent enzymes for hydrogen processing, the nickel–iron hydrogenases ([NiFe]–H2ases). 1,2 These electrocatalysts specifically mediate the redox reaction H2 " 2H + + 2e at several hundred turnovers per second. T...