Lasing in the green from a distributed feedback (DFB) structure, based upon a second order grating fabricated by replica molding in a dye-doped UV curable polymer, has been demonstrated. For a Bragg grating having a periodicity and depth of 360 ± 2 nm and 78 ± 5 nm, respectively, a coumarin 540-polymer laser operates at 535.6 nm, which is in agreement with calculations of the photonic band diag...

In this paper, we show that a few coumarin dye solutions exhibit dual amplified spontaneous emission (ASE) spectra under pulsed laser excitation, though all these solutions exhibit only one fluorescence band under steady-state conditions. The anomalous band, appearing only in ASE spectra, had been attributed to the superexciplex--a new molecular species. This is made of two excited molecules an...

Dynamic solvation of the dye, coumarin 153, is compared in an ionic liquid that forms micelles in water against the bulk solvent. This provides the unprecedented opportunity of investigating the behavior of the ionic liquid in two globally different configurations. It is proposed that the imidazolium moiety is in both cases responsible for the majority of the solvation, which manifests itself i...

This article described the synthesis and application of 6-chloro-8-fluoro-4-methylumbelliferone phosphate (CF-MUP) in analyzing acid phosphatase activity. Compared to the existing MUP, the new coumarin phosphate, CF-MUP, demonstrateed much higher sensitivity and was more robust for detecting the activity of acid phosphatase than the classic substrate 4-methylumbelliferone phosphate (MUP). The p...

A novel anchoring ligand for dye-sensitised solar cell chromophoric complexes, 1-(2,2'-bipyrid-4-yl)-1,2,3-triazole-4,5-dicarboxylic acid (dctzbpy), is described. The new dye complexes [Ru(bpy)2(dctzbpy)][PF6]2 (AS16), [Ir(ppy)2(dctzbpy)][PF6] (AS17) and [Re(dctzbpy)(CO)3Cl] (AS18) were prepared in a two stage procedure with intermediate isolation of their diester analogues, AS16-Et2, AS17-Et2 ...

Harvesting energy directly from sunlight using photovoltaic technology is an essential component of the future global energy production programs [1]. Photovoltaic devices, or solar cells, are based on the photoelectric effect, in which the incoming solar photons are absorbed in a sensitized semiconductor material freeing electric charges that are used to energize an external circuit [2]. The so...