the mononuclear complex [cu(l)(ch3cn)(pph3)]clo4, (1), (l= 2,5-diphenyl-3,4-bis(2-pyridyl)cyclopenta-2,4-dien-1-one), has been synthesized and investigated by elemental analysis, ir, 1h nmr, uv-vis spectroscopic methods and x-ray diffraction. the complex crystallizes in the non-centrosymmetric space group p212121 in accord with the asymmetric (atropisomer) cu centre. its coordination polyhedron...

an octahedral cobalt(iii) complex, trans-[(me2bpb)co(bzlan)2]clo4 (1), with h2me2bpb = n,n’-(4,5-dimethyl-1,2-phenylene)dipicolinamide and bzlan = benzylamine, has been synthesized and characterized by elemental analyses, ir, uv-vis, and 1h nmr spectroscopy. the structure of this complex has been determined by x-ray crystallography. the me2bpb2– is a di-anionic tetradentate ligand furnishing a ...

sr6nb10o30–nb2o5 nanocomposite was synthesized in 2m naoh aqueous solution. a stoichiometric 1:1 sr:nb molar ratio hydrothermal method at 120°c was used to synthesize this nanocomposite. sr(no3)2 and nb2o5 were used as raw materials. the synthesized nanomaterials were characterized by powder x-ray diffraction (pxrd) technique. it was found that sr6nb10o30 was crystallized in tetragonal crystal ...

2,5,10,13-tetraazatricyclo [12,2,2,26,9] icosa-1(16),6,8,14,17,19-hexene-3,4,11,12-tetraone tetraoxime (1a) and 2,5,11,14-tetraazatricyclo [13,3,1,16,10] icosa-1(19),6,8,10(20),15,17-hexaene-3,4,12,13-tetraonetetraoxime (1b) were obtained from condensation of 1,4- and 1,3-phenylendiamine with dichloroglyoxime, respectively. the reaction of 1,2-phenylendiamine with dichloroglyoxime resulted in t...

self-assembly of densely packed zno nanorods were grown on porous silicon (ps) substrate by low-temperature chemical bath deposition. the structural and optical properties of the obtained zno nanostructures on ps substrate were systematically studied. the strong and sharp (002) peak compared with other peaks in the x-ray diffraction (xrd) indicated thatzno nanorods formed with superior orientat...

In this paper we show that graphs of “neighbourly” cubical complexes – cubical complexes in which every pair of vertices spans a (unique) cube – have good expansion properties, using a technique based on multicommodity flows. By showing that graphs of stable set polytopes are graphs of neighbourly cubical complexes we give a new proof that graphs of stable set polytopes have edge expansion 1.

The research summarized in this thesis consists essentially of two parts. In the first, we generalize a coloring theorem of Baxter about triangulations of the plane (originally used to prove combinatorially Brouwer's fixed point theorem in two dimensions) to arbitrary dimensions and to oriented simplicial and cubical pseudomanifolds. We show that in a certain sense no other generalizations may ...

the electronic and magnetic properties of the hypothetical compounds of mc (m=al, ga and in) are investigated by using first-principle calculations and pseudopotential plane wave self-consistent field method based on density functional theory. in order to find the most stable phase of mc (m=al, ga and in), we study them in zinc-blende (zb), rocksalt (rs), wurtzite and nias crystal structures. w...

Cubical sets have a directed homology, studied in a previous paper and consisting of preordered abelian groups, with a positive cone generated by the structural cubes. By this additional information, cubical sets can provide a sort of 'noncommutative topology', agreeing with some results of noncommutative geometry but lacking the metric aspects of C*-algebras. Here, we make such similarity stri...