The dissociation of t-butyl methacrylate-methacrylic acid copolymers in dimethyl sulfoxide was analyzed by a nonaqueous potentiometric titration technique. The negative logarithm of the dissociation constant of the monomer unit of a methacrylic acid (MAA) monotonously increased with the increasing degree of dissociation corresponding to the titrant/MAA amount ratio, and was highly influenced by...

introduction: health care is one of the most important sectors in the development of each country and disparities in their distribution will reduce the level of development. the aim of this study was to examine the access to healthcare and degree of development in health care resources in the west of iran in 2011. method: this was a cross-sectional and retrospective study. the study setting was...

The kinetics of association and dissociation for the ouabain-Na+,K+-dependent ATPase complex have been studied in intact turkey erythrocytes as a function of external Na+ concentration, K+ concentration, and temperature. At free ligand concentrations substantially exceeding the concentration of available binding sites, the association reaction exhibits pseudo-first-order kinetics with an associ...

The interest in ionic liquids (ILs) as replacements for more hazardous solvents has been growing over the last years, especially industrial synthesis and liquid-liquid separations. Consequently, it is important to study their degree of dissociation (α), which quantifies ratio IL molecules dissociated into ions significantly influences viscosity, density, surface tension. In this work, ILs binar...

We introduce a generalized nonuniform mean-field formalism to describe the dissociation of weak rodlike polyelectrolytes (PEs). Our approach allows for two-sublattice symmetry breaking which in titration curves is associated with a plateau for intermediate dissociation degrees. We first test our method in the case of a single weak PE by comparison with exact enumeration studies and show that it...

Propene dissociation channels were characterized by ab initio CCSD(T)/6-311++g(d,p) calculations. Inthis work the detailed mechanism of propene dissociation to C2H4+CH2, C2H2+H+CH3, C2H2+CH4 andC3H3+H2+H have been investigated. According to our calculations, ten fragments can be classified intofive dissociated channels. Our results point out that two mechanisms come into play in the H2 eliminat...

The acid dissociation constants of the hydroxyl groups in 25, 26, 27, 28-tetrahydroxy-5, 11, 17, 23-tetrasulphonic-calix[4]arene (SC4) were determined at 25οC by a combination of potentiometric and spectrophotometric titration method. The first and second acid dissociation constants (pKa1, pKa2) were found to be 3.19 and 12.1, which demonstrated pKa shift due to intramolecular hydrogen bonding ...

for a nite group g the commutativity degree denote by d(g) and dend: d(g) = jf(x; y)jx; y 2 g; xy = yxgj jgj2 : in [2] authors found commutativity degree for some groups,in this paper we nd commuta- tivity degree for a class of groups that have high nilpontencies.

A fractal analysis is used to model the binding and dissociation kinetics of connective tissue interstitial glucose, adipose tissue interstitial glucose, insulin, and other related analytes on biosensor surfaces. The analysis provides insights into diffusion-limited analyte-receptor reactions occurring on heterogeneous biosensor surfaces. Numerical values obtained for the binding and the dissoc...