The desorption behavior of cationic-nonionic surfactant mixtures, tetradecyltrimethylammonium chloride (TTAC) and pentadecylethoxylated nonyl phenol (NP-15), at the alumina-water interface was studied. It has been found that while nonionic NP-15 itself does not adsorb at alumina-water interface, it will do so with cationic TTAC preadsorbed at the interface. During the desorption process, howeve...

Introduction X-ray standing waves (XSW) using electrons and fluorescence photons as secondary signals has become a standard technique to determine adsorbate structures. However, when a sample is irradiated by intense light, desorption of ions is also a frequently observed phenomenon which is known as photon-stimulated desorption (PSD). But, this signal is of a fundamentally different physical n...

Adsorption to GAC is an effective ·method for removing high explosives (HE) compounds from water, but no permanent treatment is achieved. Bioregeneration, which treats adsorbed contaminants by desorption and biodegradation, is being developed as a method for reducing GAC usage rates and permanently degrading RDX and HMX. Because desorption is often the limiting mass transfer mechanism in bioreg...

A study to determine the structure and activity relationships of various amine based CO2 absorbents was performed in which, the desorption of CO2 from saturated absorbent at 80 C and atmospheric pressure was measured to assess the initial desorption rate and desorption capacities at pseudo equilibrium. Evaluation of desorption capacity at 80 C will give a better understanding for more energy ef...

The desorption of molecular ices from grain surfaces is important in a number of astrophysical environments including dense molecular clouds, cometary nuclei and the surfaces and atmospheres of some planets. With this in mind, we have performed a detailed investigation of the desorption of pure water, pure methanol and pure ammonia ices from a model dust-grain surface. We have used these result...

Temperature programed desorption has been used to study the desorption kinetics and desorption energies of a set of alcohols and fluorinated alcohols adsorbed on an a-CHx film. The alcohols serve as models for the hydroxyl end groups of Fomblin Zdol, the lubricant most commonly used with the amorphous carbon overcoats sputtered onto the surfaces of magnetic data storage disks. Temperature progr...

Wehave undertaken a detailed investigation of the adsorption, desorption and thermal processing of the astrobiologically significant isomers glycolaldehyde, acetic acid andmethyl formate. Here, we present the results of laboratory infrared and temperature programmed desorption (TPD) studies of the three isomers from model interstellar ices adsorbed on a carbonaceous dust grain analogue surface....

differential scanning calorimetry (dsc), temperature programmed desorption mass spectrometry (tpd-ms) and small angle neutron scattering (sans) were used to investigate co2 uptake by the wyodak coal. adsorption of carbon dioxide on wyodak coal was studied by dsc. the exotherms evident at low temperatures are associated with the uptake of co2 suggesting that carbon dioxide interacts strongly wit...

varieties of st. john’s wort (hypericum perforatum l.) native to iran possess the largest percentage of hypercin in their leaves and flowers. isotherm curves show the relationship between the relative humidity and moisture content of the plant at a constant temperature. it is essential to understand the isotherms curves for successful storage and drying of the plant. this study used adsorption ...