The addition of a small organic electron donor, tris(p-anisyl)amine (TPAA), to an iodide/triiodide electrolyte for dye-sensitized solar cells was found give pronounced effects on charge transfer reactions. When using the dye LEG4 as sensitizer, improved cell performance found, which could be attributed extremely rapid regeneration reaction when TPAA is added. In contrast, ruthenium N719, no sig...

ont matter & 2012 0.1016/j.nanoen.2 thor. s: chldwang@mail .edu (G. Cao). Abstract A novel interface precipitation method has been developed to synthesize hierarchically structured ZnO nanocrystallite aggregates. Such synthesized ZnO nanocrystallite aggregates were demonstrated as a promising structure for high power conversion efficiency when used as photoelectrode in dye-sensitized solar cell...

Localized surface plasmon resonance (LSPR) by silver nanoparticles that are photochemically incorporated into an electrode-supported TiO(2) nanoparticulate framework enhances the extinction of a subsequently adsorbed dye (the ruthenium-containing molecule, N719). The enhancement arises from both an increase in the dye's effective absorption cross section and a modest increase in the framework s...

In this paper we focus upon the electron injection dynamics in complete nanocrystalline titanium dioxide dye-sensitized solar cells (DSSCs) employing the ruthenium bipyridyl sensitizer dye N719. Electron injection dynamics and quantum yields are studied by time-resolved single photon counting, and the results are correlated with device performance. In typical DSSC devices, electron injection ki...

Sputtered nickel oxide (NiOx) is an attractive hole-transport layer for efficient, stable, and large-area p-i-n metal-halide perovskite solar cells (PSCs). However, surface traps undesirable chemical reactions at the NiOx/perovskite interface are limiting performance of NiOx-based PSCs. To address these issues simultaneously, efficient passivation strategy by using organometallic dye molecule (...

An efficient synthetic protocol to functionalize the cyanoacrylic acid anchoring group of commercially available MK-2 dye with a highly water-stable hydroxamate anchoring group is described. Extensive characterization of this hydroxamate-modified dye (MK-2HA) reveals that the modification does not affect its favorable optoelectronic properties. Dye-sensitized solar cells (DSSCs) prepared with t...

This paper describes the surface modification of TiO2 with 3-aminopropyltriethoxysilane (APTES) followed by covalent attachment of Ru-based N719 dye molecules to TiO2 through an amide linkage for use as photoanodes (PAs) in dye-sensitized solar cells (DSSCs). Attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR) confirms the surface chemistry between the TiO2 and dye. ...

Dye-sensitized solar cell’s (DSSC) performances are enhanced by engineering the materials at interface of various device components owing to easy and inexpensive fabrication steps. Ru (II) polypyridyl-based synthetic dyes most widely used photosensitizers for DSSCs due their superior molar extinction coefficient facile interaction with metal oxide electrodes. However, these mostly expensive, as...

This report is to address the question if black γ-polymorph of cesium tin tri-iodide (B-γ-CsSnI3) can be used as a solid-state hole-transport material in the conventional DSSCs with the N719 dye to replace the liquid electrolyte as reported by I. Chung et al. on Nature 485, 486, (2012). Here we demonstrate rigorously that B-γ-CsSnI3 is not energetically possible to collect photogenerated holes ...