The mechanism of the electrochemical reduction of nitric oxide (NO) by hemin adsorbed at pyrolitic graphite was investigated. The selectivity of NO reduction was probed by combining the rotating ring disk electrode (RRDE) technique with a newly developed technique called on-line electrochemical mass spectroscopy (OLEMS). These techniques show that NO reduction by adsorbed heme groups results in...

Here we review the recent applications of ion transfer (IT) at the interface between two immiscible electrolyte solutions (ITIES) for electrochemical sensing and imaging. In particular, we focus on the development and recent applications of the nanopipet-supported ITIES and double-polymer-modified electrode, which enable the dynamic electrochemical measurements of IT at nanoscopic and macroscop...

Considering exponential dependence of currents on double-layer voltage and the feedback effect of the electrolyte resistance, a distance effect in electrochemical micromachining is found, namely that both time constant and double-layer voltage depend on the separation of electrodes. The double-layer voltage is the real voltage used in processing. Under DC voltage, the apparent voltages between ...

Electrochemical systems with high capacities demand devices for electrochemical impedance spectroscopy (EIS) with ultra-low frequencies (in order of mHz), that are almost impossible to accomplish with analogue techniques, but this becomes possible by using a computer technique and accompanying digital equipment. Recently, an original software and hardware for electrochemical measurements, inten...

This paper deals with the development of an electrochemical sensor base on Trypan Blue (TB) towards the determination of Dopamine (DA). An electrochemical sensor was fabricated by the electropolymerization of TB onto the Carbon paste electrode (CPE) using cyclic voltammetry (CV) technique. The polymerized TB modified CPE (Poly(TB)MCPE) was characterized using Electrochemical impedance spectrosc...

The first papers related to the scanning electrochemical microscopy (SECM) were published in the nineties of the 20th century [1, 2]. This technique is based on the scanning of the studied surface by ultramicroelectrode (UME) and electrochemical analysis of surface [1]. Such technique gives us an electrochemical picture of the surface. SECM employs an UME probe (tip) to induce chemical changes ...

vanillin offers interesting possibilities for corrosion inhibition because of its safe use and highsolubility in water. the effect of vanillin on the corrosion inhibition of aisi 304 stainless steel in0.5m h2so4 solution has been studied using potentiodynamic polarization and electrochemicalimpedance spectroscopy (eis). furthermore, this paper demonstrates that the electrochemical noise(en) tec...

the combination of graphene (gr) and nickel oxide nanoparticles (nio nps) yields nanostructured electrochemical sensor formed a novel kind of structurally uniform and electrocatalytic activity material. in cyclic voltammetry (cv) studies, in the presence of ep, nio/gr composite modified electrode shows a significantly higher current response for ep oxidation. based on differential pulse voltamm...

In the previous lecture, we leant about impedance spectroscopy. Electrochemical impedance spectroscopy is the technique where the cell or electrode impedance is platted versus frequency. Thus, the impedance is measured as a function of the frequency of the AC source. Electrochemical impedance spectroscopy is a useful method for investigating porous electrodes, which are extensively used in the ...

Nucleic acid amplification is a gold standard technique for analyzing a tiny amount of nucleotides in molecular biology, clinical diagnostics, food safety, and environmental testing. Electrical and electrochemical monitoring of the amplification process draws attention over conventional optical methods because of the amenability toward point-of-care applications as there is a growing demand for...