In the present study, the effect of porosity on the cathode microstructure (50:50 wt. % LSM: YSZ) of a Solid Oxide Fuel Cell (SOFC) has been examined. A 3-D finite element method for Mixed Ionic and Electronic Conducting Cathodes (MIEC) is presented to study the effects of porosity on cell performance. Each microstructure was realized using the Monte Carlo approach with the isotropic type of gr...

The interaction of ferrocene-1,1(')-dithiol (FDT) with two parallel Ag(111) surfaces has been theoretically studied at density-functional level. The effect of surface defects on the energetic and electronic structure was investigated. The electronic transport properties are studied with the nonequilibrium Green's function approach. The adsorption geometry has a strong effect on the electronic l...

The change in conductivity of Fe and Ti implanted if-sputtered layers of yttria-stabilized zirconia (YSZ) was studied as a function of the temperature (400-800 °C) and oxygen partial pressure. In an oxidized state and in the temperature range of 400600 ° C, the conductivity of the Fe implanted YSZ film ( 15 keV, 8 × 10 '6 at.cm 2) was dominated by the n-type electronic conductivity of a thin Fe...

There is increasing interest in electromagnetic interference (EMI) shielding due to the serious electromagnetic environment pollution caused by the continuously increased use of the electrical products and electronic devices. Electrical conductivity and EMI shielding effectiveness (SE) of composite materials made from silicone rubber with carbon powder and ferrite powder have been studied in mi...

The properties of solid oxide fuel cell (SOFC) anode functional layers prepared by impregnation of 1 wt % Pd and 10 wt % ceria into porous scaffolds of either Y0.04Ce0.48Zr0.48O2 (CZY) or composites of La0.3Sr0.7TiO3 (LST) and yttria-stabilized zirconia (YSZ) were examined to determine whether these scaffold materials would have sufficient electronic and ionic conductivity. Laminated tapes were...

The electronic properties of a Z-DNA crystal synthesized in the laboratory are investigated by means of density-functional theory Car-Parrinello calculations. The electronic structure has a gap of only 1.28 eV. This separates a manifold of 12 occupied states which came from the pi guanine orbitals from the lowest empty states in which the electron is transferred to the Na+ from PO-4 groups and ...

Mixed-conducting lithium-ion doped emeraldine polyaniline (PAni)–polyethylene oxide (PEO) blends have been developed to achieve an optimal electronic– ionic conductivity balance in nano-tin composite anodes. Electrochemical evaluation was performed on the anodes with differing electrode preparation procedures, doping methods and PEO contents. Results indicate that both good electronic and ionic...

Abstract. In this chapter, we study the electronic structure of arbitrarily stacked multilayer graphene in the absence or presence of magnetic field. The energy band structure and the Landau level spectrum are obtained using a π-orbital continuum model with nearest-neighbor intralayer and interlayer tunneling terms. Using degenerate state perturbation theory, we analyze the low-energy effective...

The optical conductivity of high quality decagonal quasicrystals of Ales Co&qCu&s and A162Co~5CupoSi3 shows a strong anisotropy between the periodic and the quasiperiodic directions. We suggest that this is due to the dramatic enhancement of scattering in the quasiperiodic planes. The analysis of the conductivity reveals a drastic difFerence between the electronic structure of the decagonal qua...