In the present work, the solidification process was simulated in both macroscopic and microscopic scales. Two-dimensional heat transfer equation for conduction was applied for macroscopic modeling using enthalpy formulation and finite element method. In order to decrease execution time and/or memory capacity in finite analysis, skyline mathematical technique was adapted. The microenthalpy metho...

Recent work has sought to extract the asymmetry energy at very low density from observables in heavyion collisions. The logic employed starts from the assumption that the fragment yields are determined by a minimization of the Helmholtz free energy. As volume is in reality unconstrained, nor can a single freeze-out volume be expected, the physical relevance of the Helmholtz free energy must be ...

13 The sublimation enthalpy of cubane, a key reference material for force field and quantum mechanical computations, was measured by combining the vaporization enthalpy at T = 298.15 K to the sum of the fusion enthalpy measured at T = 405 K and a solid–solid phase transition that occurs at T = 394 K. The fusion and solid–solid phase transitions were measured previously. A sublimation enthalpy v...

The rapid melting of silicon film due to the absorption of a CW laser beam radiation is studied. The silicon film melting and recrystallization is mainly controlled by the temperature distribution in the semiconductor. The enthalpy technique for the solution of phase change problems is used in an explicit finite difference form to calculate the transient temperature distribution in the silicon ...

The enthalpy changes for phosphorylating and nonphosphorylating mitochondrial oxidation of succinate by ferricyanide were studied by heatburst microcalorimetry. The enthalpy change observed with a nonphosphorylating system involving sonically disrupted mitochondria agreed with the calculated enthalpy change. The enthalpy changes for phosphorylating and uncoupled systems involving intact mitocho...

BACKGROUND Heat stress evaluation and timely notification, especially using meteorological data is an important issue attracted attention in recent years. Therefore, this study aimed at answering the following research questions: 1) can enthalpy as a common environmental parameter reported by meteorological agencies be applied accurately for evaluation of thermal condition of outdoor settings, ...

The numerical solution of one-dimensional phase change problems using an adaptive moving mesh method. An adaptive moving mesh method is developed for the numerical solution of an enthalpy formulation of heat conduction problems with a phase change. The algorithm is based on a very simple mesh modiication strategy that allows the smooth evolution of mesh nodes to track interfaces. At each time s...

Abs t rac t -The persistence of many seemingly metastable mineral assemblages in sediments and soils is commonly attributed to their sluggish transformation to the stable-phase assemblage. Although undoubtedly kinetics plays a major role, this study shows that thermodynamic factors, particularly surface energy, significantly influence the free energy. Enthalpies of formation of boehmite samples...