Non-adiabatic dynamics of the acetylene cation is investigated using mixed quantum-classical dynamics based on trajectory surface hopping. To describe the non-adiabatic effects, two surface hopping methods are used, namely, Tully's fewest switches and Landau-Zener surface hopping. Similarities and differences between the results based on those two methods are discussed. We find that the photoio...

Optimization of continuous synthesis of high purity carbon nanotubes (CNTs) using chemical vapour deposition (CVD) method was studied experimentally and theoretically. Iron pentacarbonyl (Fe(CO)5), acetylene (C2H2) and Ar were used as the catalyst source, carbon source and carrier gas respectively. The synthesis temperature and flow rates of Ar and acetylene were optimized to produce CNTs at a ...

In previous communications from this laboratory on the fate of ethylene in avocados, it was shown that approximately 127, of the radioactivity of metabolized ethylene-3H appeared in the methyl group of toluene (1) whereas only approximately 0.2% of the radioactivity of metabolized ethylene-14C appeared in toluene (2). On the other hand, benzene produced by the metabolism of ethylene-3H and ethy...

Kinetic studies reported here have shown that acetylene is a potent reversible inhibitor of reductive dehalogenation of trichloroethene (TCE) and vinyl chloride (VC) by a mixed dehalogenating anaerobic culture. The mixed culture was enriched from a contaminated site in Corvallis, OR, and exhibited methanogenic, acetogenic, and reductive dehalogenation activities. The H2-fed culture transformed ...

Optimization of continuous synthesis of high purity carbon nanotubes (CNTs) using chemical vapour deposition (CVD) method was studied experimentally and theoretically. Iron pentacarbonyl (Fe(CO)5), acetylene (C2H...

Kinetic studies reported here have shown that acetylene is a potent reversible inhibitor of reductive dehalogenation of trichloroethene (TCE) and vinyl chloride (VC) by a mixed dehalogenating anaerobic culture. The mixed culture was enriched from a contaminated site in Corvallis, OR, and exhibited methanogenic, acetogenic, and reductive dehalogenation activities. The H2-fed culture transformed ...

Acetylene reduction activity of intact rice plants was measured in closed assay chambers with plants grown in water culture. Acetylene was added to the liquid medium, and the ethylene formed was measured from both gas and liquid phases. After cutoff of mineral nitrogen supply and inoculation of fresh soil, rice plants grown from the seedling stage in water culture exhibited acetylene reduction ...

The inhibition effects and mechanisms of chlorinated methane and acetylene on methanogenesis in the anaerobic digestion process of the biodegradable wastes were investigated. It was found that both chloroform and acetylene could effectively inhibit methanogens while the biodegradability of the wastes was not affected. Acetylene inhibited the activity of methanogens, while chloroform inhibited m...