Hydrogen peroxide reacts with ferrous Ascaris hemoglobin and converts it to oxyhemoglobin in a sequence of two reactions. The first is the reaction of ferrous Ascaris hemoglobin with hydrogen peroxide to form a stable product; the second is the reaction of this product with hydrogen peroxide to form oxyhemoglobin. Both reactions follow second order kinetics, since they are first order with resp...

R ECENTLY a new reagent was proposed for the determination of cholesterol (1, 2). This reagent was purported to be saturated ferrous sulfate in glacial acetic acid. Since it has been reported that ferrous sulfate is qualitatively insoluble in anhydrous acetic acid (3, 4) and that ferrous iron is “subject to pronounced air oxidation in glacial acetic acid” (5), it was felt that several factors s...

the term biomining have been coined to refer to the use of microorganisms in mining processes as in the biooxidation of refractory gold minerals. the biooxidation of refractory gold ores presents similar characteristics when compared with roasting and pressure oxidation. almost without exception, microbial extraction procedures are more environmentally friendly. the isolated bacteria in this st...

The involvement of metal in oxidation and coupled phosphorylation by cell-free preparations of Mycobacterium phlei was examined. The oxidation of succinate was inhibited by metal-chelating agents, but with /3-hydroxybutyrate, chelating agents exhibited an uncoupling effect. The site of inhibition was found to be between the flavoprotein and the cytochrome b regions of the electron transport cha...

Schwertmannite-mediated removal of arsenic from contaminated water has attracted increasing attention. However, schwertmannite chemical synthesis behavior under different H2O2 supply rates for ferrous ions oxidation is unclear. This study investigated pH, ferrous ions oxidation efficiency, and total iron precipitation efficiency during schwertmannite synthesis by adding H2O2 into FeSO4 · 7H2O s...

Ferrobacillus ferrooxidans was isolated and named by Leathen and Braley (1) in 1954 and reported to be an obligate chemoautotroph which utilizes the oxidation of inorganic ferrous iron as a primary energy source. A somewhat similar bacterium, called Thiobaeillus ferrooxiduns, had previously been isolated by Cohner, Temple, and Hinkle (2) and characterized as an obligate chemoautotroph which wou...

The crenarchaeal order Sulfolobales collectively contain at least five major terminal oxidase complexes. Based on genome sequence information, all five complexes are found only in Metallosphaera sedula and Sulfolobus tokodaii, the two sequenced Sulfolobales capable of iron oxidization. While specific respiratory complexes in certain Sulfolobales have been characterized previously as proton pump...

Oil emulsion and raw and cooked tissue homogenates were used to determine the mechanisms of various iron forms on the catalysis of lipid peroxidation. Flax oil (0.25 g) was blended with 160 mL maleate buffer (0.1 M, pH 6.5) to prepare an oil emulsion. Raw or cooked turkey leg meat was used to prepare meat homogenates. Samples were prepared by adding iron from each of the various sources, reacti...