Conventionally, methane is reformed into syngas, and subsequently converted into C1-oxygenates (methanol and formaldehyde). A novel option is the catalyst-free single-step conversion of methane to C1-oxygenates. This study presents a comprehensive model of methane partial oxidation to formaldehyde as an intermediate chemical species in methane oxidation process using microreactor. The dependenc...

The term “Natural Attenuation” (NA) has been defined as “naturally occurring processes in soil and groundwater environments that act without human intervention to reduce the mass, toxicity, mobility, volume, or concentration of contaminants in those media” (Wiedemeier et al., 1999). This popular definition goes on to mention that the “in-situ” processes of NA include biodegradation, dispersion,...

A strain that efficiently degraded methyl tert-butyl ether (MTBE) was obtained by initial selection on the recalcitrant compound tert-butyl alcohol (TBA). This strain, a gram-positive methylotrophic bacterium identified as Mycobacterium austroafricanum IFP 2012, was also able to degrade tert-amyl methyl ether and tert-amyl alcohol. Ethyl tert-butyl ether was weakly degraded. tert-Butyl formate ...

We have recently introduced several important improvements in the measurement of distillation curves for complex fluids. The modifications provide for (1) a composition explicit data channel for each distillate fraction (for both qualitative and quantitative analysis), (2) temperature measurements that are true thermodynamic state points that can be modeled with an equation of state, (3) temper...

Sprague-Dawley rats were exposed via inhalation to vapor condensates of either gasoline or gasoline combined with various fuel oxygenates to assess potential neurotoxicity of evaporative emissions. Test articles included vapor condensates prepared from "baseline gasoline" (BGVC), or gasoline combined with methyl tertiary butyl ether (G/MTBE), ethyl t-butyl ether (G/ETBE), t-amyl methyl ether (G...

Diesel engines are major contributors of various types of air polluting exhaust gasses such as Particulate Matter (PM), Carbon monoxide (CO), Oxides of Nitrogen (NOx), Sulfur, and other harmful compounds. It has been shown that formation of these air pollutants can be significantly reduced by blending oxygenates into the base diesel. Ethanol blended diesel (e-diesel) is a cleaner burning altern...

The emission of carbon monoxide, greenhouse gases (e.g., dioxides), hydrocarbon, and particulate matter can be reduced by applying oxygenated additives as a blend to combustible hydrocarbon fuels. However, conventional oxygenates, such dimethyl ether methyl t-butyl ether, are sourced from non-renewable feedstocks. This study presents critical review on the catalytic synthesis furanic compounds,...

This work explores the synergies during combined reactions of n-pentane (nC5) with oxygenates (methanol or dimethyl ether, OX). The experimental runs have been carried out in a packed bed reactor at 500 °C, using high silica HZSM-5 zeolite-based catalyst different oxygenate-to-n-pentane (OX/nC5) ratios feed. A significant enhancement conversion occurs for low OX/nC5 feed (0.1?0.25), especially ...