sulfonic acid functionalized sba-15 (sba-pr-so3h) with pore size 6 nm as an efficient heterogeneous nanoporous solid acid catalyst exhibited good catalytic activity in the biginelli-like reaction in the synthesis of spiroheterobicyclic rings with good yield and good recyclability. spiro-pyrimidinethiones/spiro-pyrimidinones-barbituric acid derivatives were synthesized in a simple and efficient ...

Abstract Nanoporous gold was functionalized with a photosensitizer, zinc(II) phthalocyanine derivative. Such systems are active for the generation of reactive singlet oxygen which can be used photocatalytic oxidation reactions. This study aims to demonstrate versatility such an approach, in terms substrates and employed solvent, only possible truly heterogeneous catalytic system. The activity h...

The preparation and characterization of coatings made from polydiacetylene colloids on nano- and microporous membranes and their potential for the detection of microorganisms are presented.

Composite materials, especially polymer matrix composites, have been intensively studied for energy absorption applications. When the temperature is close to or higher than the glass transition temperature (Tg), the polymer matrix is usually viscoelastic. With an external loading, either dynamic or quasi-static, the relaxation of the network polymer chains would cause a considerable energy diss...

Phosphate was captured from aqueous solutions by cationic metal-EDA complexes anchored inside mesoporous silica MCM-41 supports (Cu(II)-EDA-SAMMS and Fe(III)-EDA-SAMMS). Fe-EDA-SAMMS was more effective at capturing phosphate than the Cu-EDA-SAMMS and was further studied for matrix effects (e.g., pH, ionic strength, and competing anions) and sorption performance (e.g., capacity and rate). The ad...

An innovative and low-cost method is proposed for the detection and discrimination of indole-positive pathogen bacteria. The method allows the non-invasive detection of gaseous indole, released by bacteria, with nanoporous colorimetric sensors. The innovation comes from the use of nanoporous matrices doped with 4-(dimethylamino)-cinnamaldehyde, which act as sponges to trap and concentrate the t...

The behaviour of a p-xylene-based lyophobic nanoporous carbon system under high hydrostatic pressures is investigated. As the pressure is increased to a critical value, the nanopore surfaces between graphene layers are exposed to the liquid phase, leading to a considerable increase in solid–liquid interfacial energy. During unloading, defiltration does not occur until the pressure is much lower...