In the present study, the interaction between nano-TiO2 and lysozyme was investigated by the method of UV-Vis detection and fluorescence spectroscopic techniques. The thermal denaturation of lysozyme has been investigated in the presence and absence of nano-TiO2 over the temperature range (293-373) K in different buffer and pH, using temperature scanning spectrosc...

The essential oil from the aerial parts of Iranian and British Thymus vulgaris L. were obtained by hydro distillation and analyzed by gas chromatography (GC) and gas chromatographymass spectrometry (GC-MS). Forty two components were identified in the Iranian Th. vulgaris essential oil that represented 99.06% of the oils. The major components were thymol (60.54%), γTerpinene (9.47%), p-cymene (8...

There is increasing observational evidence that hot, highly ionized interstellar and intergalactic gas plays a significant role in the evolution of galaxies in the local universe. The primary spectral diagnostics of the warm-hot interstellar/intergalactic medium are ultraviolet and X-ray absorption lines of Ovi and Ovii. In this paper, I summarize some of the recent highlights of spectroscopic ...

Titanium (Ti) is a relatively abundant element that has found growing applications in medical science and recently some of Ti compounds are introduced as anticancer drugs. In spite of very limited data which exist on the Ti metabolism, some proteins might be involved in the mechanism of action of Ti. Up to our knowledge, there is not any report in the literature concerning binding of Ti to apol...

Through benchmark studies, we explore the performance of PBE density functional theory, with and without Grimme's dispersion correction (DFT-D3), in predicting spectroscopic properties for molecules interacting with rare gas matrices. Here, a periodic-dispersion corrected model of matrix embedding is used for the first time. We use PBE-D3 to determine the equilibrium structures and harmonic vib...

We report the photoelectron spectrum of anionic N-acetylproline, (N-AcPro)(-), measured with 3.49 eV photons. This spectrum, which consists of a band centered at an electron binding energy of 1.4 eV and a higher energy spectral tail, confirms that N-acetylproline forms a valence anion in the gas phase. The neutrals and anions of N-AcPro were also studied computationally at the B3LYP∕6-31++G(d,p...

The aim of this study was to screen for microorganism that able to utilize 3-N-trimethylamino-1-propanol (homocholine) as a sole source of carbon and nitrogen. The aerobic degradation of homocholine has been found by a gram-positive Rhodococcus sp. bacterium isolated from soil. The isolate was identified as Rhodococcus sp. strain A4 based on the phenotypic features, physiologic and biochemical ...

The amino acid L-arginine is a component of proteins and is involved in several metabolic pathways, including the urea cycle, the synthesis of creatine and the generation of nitric oxide [1]. In the last 2 years it has been established that arginine can also be decarboxylated, resulting in the formation of agmatine, 4(aminobutyl)guanidine. The enzyme arginine decarboxylase was thought to be pre...

The field of gas phase photochemistry has progressed explosively in the past few decades due to the development of ultra fast high power lasers. Unique properties of lasers such as monochromaticity, coherence, tunability over a wide wavelength range and high intensity makes them a powerful pump and probe tool for a number of spectroscopic as well as photochemical studies like laser induced fluo...