By employing molecular dynamics simulations, we explore the dynamics of NPs in semiflexible ring polymer nanocomposite melts. A novel glass transition is observed for NPs in semiflexible ring polymer melts as the bending energy (Kb) of ring polymers increases. For NPs in flexible ring polymer melts (Kb = 0), NPs move in the classic diffusive behavior. However, for NPs in semiflexible ring polym...

We study the influence of composition changes on the glass transition of binary hard disk and hard sphere mixtures in the framework of mode coupling theory. We derive a general expression for the slope of a glass transition line. Applied to the binary mixture in the low concentration limits, this method allows a fast prediction of some properties of the glass transition lines. The glass transit...

We perform molecular dynamics simulations of the glass transition through isobaric and isochoric cooling of a model polymeric material. In general, excellent agreement between the simulation results and the existing experimental trends is observed. The glass transition temperature (Tg) is found to be a function of pressure under isobaric conditions and specific volume under isochoric conditions...

This manuscript studied the effect of counterion on the glass transition and recrystallization behavior of amorphous salts of prazosin. Three amorphous salts of prazosin, namely, prazosin hydrochloride, prazosin mesylate and prazosin tosylate were prepared by spray drying, and characterized by optical-polarized microscopy, differential scanning calorimetry and powder X-ray diffraction. Modulate...

Colloidal gel and glass transitions are investigated using the idealized mode coupling theory (MCT) for model systems characterized by short-range attractive interactions. Results are presented for adhesive hard sphere and hard core attractive Yukawa systems. According to MCT, the former system shows a critical glass transition concentration that increases significantly with introduction of a w...

Oxynitride glasses are found as grain boundary phases in silicon nitride ceramics. They are effectively alumino-silicate glasses in which nitrogen substitutes for oxygen in the glass network, and this causes increases in glass transition and softening temperatures, viscosities (by two to three orders of magnitude), elastic moduli and microhardness. Calcium silicate-based glasses containing fluo...

Birefringence of oxide glass bers drawn from glass melts through an ori ce has been detected previously [1, 2]. This birefringence is a measure of anisotropy in glass structure that can in uence ber performance properties. Birefringence is produced during ber drawing as the ber is rapidly stretched in the viscoelastic glass transition range. The birefringence is \frozen" into the glass during r...

The transition from a liquid to a glass in colloidal suspensions of particles interacting through a hard core plus an attractive square-well potential is studied within the mode-coupling-theory framework. When the width of the attractive potential is much shorter than the hard-core diameter, a reentrant behavior of the liquid-glass line and a glass-glass-transition line are found in the tempera...

(1 - x)(Bi1/2Na1/2)TiO3 - xBaTiO3 has been the most studied Pb-free piezoelectric material in the last decade; however, puzzles still remain about its phase transitions, especially around the important morphotropic phase boundary (MPB). By introducing the strain glass transition concept from the ferroelastic field, it was found that the phase transition from tetragonal (T, P4bm) to rhombohedral...