Time resolved optical emission spectroscopy is employed to study the expansion dynamics of C2 species in a graphite plasma produced during the Nd : YAG ablation. At low laser fluences a single peak distribution with low kinetic energy is observed. At higher fluences a twin peak distribution is found. It has been noted that these double peak time of flight distribution splits into a triple peak ...

Palladium nanoparticles encapsulated into graphite (Pd–graphite intercalation compound: Pd–GIC) were produced from two kinds of graphite, natural graphite (average flake size: 270 mm) and kish graphite (average flake size: 15 mm). Hydrogen storage properties of Pd– GIC have been investigated by means of differential scanning calorimetry (DSC) between 473 and 573 K at 1.0 MPa hydrogen pressure. ...

Graphite, as the most common anode for commercial Li-ion batteries, has been reported to have a very low capacity when used as a Na-ion battery anode. It is well known that electrochemical insertion of Na(+) into graphite is significantly hindered by the insufficient interlayer spacing. Here we report expanded graphite as a Na-ion battery anode. Prepared through a process of oxidation and parti...

A Pd-encapsulated graphite electrode was used as the negative electrode in Li-ion cells. Through dispersion of ultrafine nanoparticles of palladium on the surface of graphite, the interfacial properties of the carbon surface were modified. The presence of the palladium Ž . dramatically reduces the initial irreversible capacity of the graphite in propylene carbonate PC -based electrolyte. Pallad...

The properties, interactions, and reactions of cyclic water clusters (H(2)O)(n=1-5) on model systems for a graphite surface have been studied using pure B3LYP, dispersion-augmented density functional tight binding (DFTB-D), and integrated ONIOM(B3LYP:DFTB-D) methods. Coronene C(24)H(12) as well as polycircumcoronenes C(96)H(24) and C(216)H(36) in monolayer, bilayer, and trilayer arrangements we...

In this paper, an approach to generate surrogate models constructed by radial basis function networks (RBFN) with a priori bias is presented. RBFN as a weighted combination of radial basis functions only, might become singular and no interpolation is found. The standard approach to avoid this is to add a polynomial bias, where the bias is defined by imposing orthogonality conditions between the...

Ureilites and carbonaceous chondrites: The origin of ureilite meteorites has been consistently regarded as problematic [1]. A distinctive feature of ureilites is that they contain carbonaceous matter up to 6 wt. %, particularly in the form of graphite in veinlets between silicate (mostly olivine) crystals, and along their cleavage planes. The carbonaceous matter within them suggests a relations...

We report new three-dimensional (3D)-nanostructured MoS2-carbonaceous materials in which MoS2 sheets are intercalated between the graphite layers that possess a multiply repeated graphite/MoS2/graphite structure which prevents the aggregation of MoS2 and diffusion of sulfur from carbonaceous materials, enhancing the cycling stability of Li-ion batteries. We developed an efficient and scalable p...

The erosion of highly-ordered pyrolytic graphite (HOPG) caused by exposure to hyperthermal atomic oe p) atoms was explored. Profilometry has revealed that the overall erosion yield is linear with respect to increasing atomic oxygen exposure at a constant sample temperature of 373 K. Atomic force microscopy (AFM) was employed to image the eroded material that contains numerous nanoscale to micro...