A series of 1-ethyl-1'-benzyl-4,4'-bipyridinium compounds with different counter anions (BEV-X2, where the X is Cl, Br, I, PF6, ClO4) were synthesized. By using of NMR, MS, electrochemistry, Na2S2O4-induced redox chemistry, and UV-Vis, the role of the different counter anions in the host-guest chemistry of cucurbit[8]uril (CB[8]) was studied for the first time. The result demonstrated that BEV-...

Host-guest chemistry is usually carried out in either water or organic solvents. To investigate the utility of alternative solvents, three different coordination cages were dissolved in neat ionic liquids. By using (19) F NMR spectroscopy to monitor the presence of free and bound guest molecules, all three cages were demonstrated to be stable and capable of encapsulating guests in ionic solutio...

Hosting virtual servers on a shared physical hardware by means of hardware virtualization is common use at data centers, web hosters, and research facilities. All virtualization platforms include isolation techniques that restrict resource consumption of the virtual guest systems. Therefore, they setup quotas for the virtual guest systems on the use of processors, memory, and hard disk of the h...

Executing VMM-provided code with privileged access to specific hardware and VMM resources within an untrusted guest operating system can enable new mechanisms to enhance functionality, performance, and adaptability. We present a software technique, guarded execution of privileged code in the guest, that allows the VMM to provide this capability, as well as an implementation for Linux guests in ...

Based on the principle of the equivolumetric model, the multiple scattering from two-dimensional composite gyrotropic bianisotropic cylinders (GBC's) possessing a certain magnetic group of symmetry is studied by using the indirect modeling technique. At first, a mathematical formulation for the problem is carried out and its solution expressed in terms of a system of simultaneous linear equatio...

Supramolecular interactions of polynitroxides with c-cyclodextrin (c-CD) were used to control intramolecular electron spin–spin exchange couplings in these stable radicals. In the absence of c-CD, the binitroxide T2 and trinitroxide T3 showed strong spin–spin coupling as evidenced by the high exchange coupling constant of J = 120 MHz for T2 in its EPR spectra. Host/guest complexes are formed up...

General rights Copyright for the publications made accessible via the Edinburgh Research Explorer is retained by the author(s) and / or other copyright owners and it is a condition of accessing these publications that users recognise and abide by the legal requirements associated with these rights. Take down policy The University of Edinburgh has made every reasonable effort to ensure that Edin...

General rights Copyright for the publications made accessible via the Edinburgh Research Explorer is retained by the author(s) and / or other copyright owners and it is a condition of accessing these publications that users recognise and abide by the legal requirements associated with these rights. Take down policy The University of Edinburgh has made every reasonable effort to ensure that Edin...

Virtual machine introspection (VMI) describes the method of monitoring, analyzing, and manipulating the state of a virtual machine from the hypervisor level. This lends itself to many security applications, though they all share a single fundamental challenge: One must address the fact that the hypervisor has no semantic knowledge about what the system state means (e. g., where key data structu...

Reliability of a performance model is quintessential to the robust resource management of applications on the cloud platform. Existing studies show that the contention for shared I/O induces temporal performance variations in a guest VM and heterogeneity in the underlying hardware leads to relative performance difference between guest VMs of the same abstract type. In this work, we demonstrate ...