نتایج جستجو برای: iodoarenes

تعداد نتایج: 72  

2017
Yun Yang Lijuan Zhang Guo-Jun Deng Hang Gong

A practical, efficient, and operationally simple strategy for the ipsoiododecarboxylation and di-iodination of aromatic carboxylic acids using the low-cost commercial reagent succinimide (NIS) as iodine source is reported. This iodination or di-iodination process can be easily controlled through reaction conditions, thereby providing corresponding iodination or di-iodination products with high ...

Journal: :The Journal of organic chemistry 2001
A J McNeil R J Hinkle E A Rouse Q A Thomas D B Thomas

Generation of vinyl cations is facile by fragmentation of alkenyl(aryl)iodonium trifluoromethanesulfonates. Kinetics and electronic effects were probed by (1)H NMR spectroscopy in CDCl(3). Products of fragmentation include six enol triflate isomers in addition to iodoarenes. The enol triflates arise from direct reaction of a triflate anion with the starting iodonium salts as well as triflate re...

2017
Lorenzo Cavina Dion van der Born Peter H M Klaren Martin C Feiters Otto C Boerman Floris P J T Rutjes

Radioiodinated pharmaceuticals are convenient tracers for clinical and research investigations because of the relatively long half-lives of radioactive iodine isotopes (i.e., 123I, 124I, and 131I) and the ease of their chemical insertion. Their application in radionuclide imaging and therapy may, however, be hampered by poor in vivo stability of the C-I bond. After an overview of the use of iod...

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