The new synthesized thiomacrocyclic ionophore 4-phenyl-4-sulfide-11-(1-oxodecyl)-1,7-dithia-11-aza-4-phosphacyclotetradecane has proven to form Langmuir and Langmuir-Blodgett (LB) films. This ionophore shows a large affinity for copper(II) ions. Thus, the influence of the subphase composition on the surface pressure-area isotherms has been studied. The LB films have been observed by AFM and the...

In this work, we report the synthesis and characterization of a novel series of first and second generation Fréchet type dendrons bearing amino-nitro substituted azobenzene units and tetra(ethylene glycol) spacers. These compounds were fully characterized by FTIR, 1H and 13C-NMR spectroscopies, and their molecular weights were determined by MALDI-TOF-MS. The thermal properties of the obtained d...

The relationship between the mass uptake and the swelling of arachidic acid Langmuir-Blodgett (LB) films exposed to water vapor was investigated. Combining sorption data from the quartz crystal microbalance with swelling data from the surface forces apparatus (SFA), it was found that films exposed to water vapor ( approximately 75% RH) absorb 0.22 moles water/mole LB film with an associated swe...

Langmuir films of 4-{[4-({4-[(trimethylsilyl)ethynyl]phenyl}ethynyl)phenyl]ethynyl} benzenaminium chloride ([1 H]Cl) undergo anion metathesis when assembled on an aqueous auric acid (HAuCl4 ) subphase. Subsequent transfer to solid supports gives well-formed Langmuir-Blodgett (LB) monolayers of [1 H]AuCl4 in which the trimethylsilyl group serves as the surface contacting group. Photoreduction of...

New sal₂(trien) ligands that contain alkoxy substituents of various length in meta position of the phenolate entities were coordinated to electronically and magnetically active iron(III) and cobalt(III) centers. The electrochemical and spectroscopic properties of these amphiphilic complexes are virtually unaffected upon alteration of the alkoxy substituents, thus providing a system in which the...

The effect of electron irradiation on the ferroelectric properties ofLangmuir-Blodgett films of the copolymer poly(vinylidene fluoride-trifluoroethylene) isinvestigated using 1.26 MeV electrons with dosages from 16 to 110 Mrad. Films wereirradiated in the ferroelectric state to investigate the effect of defect introduction inultrathin films. Electron irradiation is known to ...