The reactions of 1 - chloro - 2 - nitro benzene with 2 - Amino thio phenol yield the 2 - ( ( nitro phenyl ) thio ) aniline and then 2 , 2' - thio dianiline of this compound was prepared . Also the symmetrical potentially pentadentate N 2 O 2 S Schiff base ligand 2 , 2' - ( ( ( thio bis (1 , 2 - phenylene ) ) bis ( azanilidene ) ) bis ( methenilidene ) ) diphenol ( H 2 L ) obtain by added salicy...

The mononuclear complex [Cu(L)(CH3CN)(PPh3)]ClO4, (1), (L= 2,5-diphenyl-3,4-bis(2-pyridyl)cyclopenta-2,4-dien-1-one), has been synthesized and investigated by elemental analysis, IR, 1H NMR, UV-Vis spectroscopic methods and X-ray diffraction. The complex crystallizes in the non-centrosymmetric space group P212121 in accord with the asymmetric (atropisomer) Cu centre. Its coordination polyhedron...

Here, we report the synthesis of a Schiff-base mixed-ligand complex of cadmium(ІІ) in bulk and nano-scales via the precipitation and sonochemical methods, respectively. The complex formula is [Cd(3-bpdh)(3-bpdb)Cl2]n (1), where the ligands are 3-bpdh = 2,5-bis(3-pyridyl)-3,4-diaza-2,4-hexadiene and 3-bpdb = 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene. The structure of mixed-ligand complex (1) wa...

The complex of Ce(III), [ Ce (PHENSC) (H 0) ] (C10 ) , was synthesized using the PHENSC, a hexadentate ligand,2,9-diformyl-1,lO- Phenanthroline bis (semicarbazone), and characterized by X-ray diffraction. The cerium atom has an unusual coordination number of ten involving six donor atoms of the planar ligand in the equatorial plane and four oxygen atoms from four axial water molecules. The...

In this work, a new spectrophotometric method for the determination of trace amount of Cobalt (ІІ) ionwas investigated and the stability constant of the related complex was evaluated 2.174 × 104. In the Cobalt(ІІ)-piroxicam complex, the maximum absorbance wavelength is 570 nm and the linearity of calibrationcurve was investigated (5-10 ppm). The relative standard deviation for seven replicate e...

Mo(III), Fe(III), Cd(II), Zn(II), Cu(II) complexes based on Tris[2-salicylaldeneimino)ethyl]amine (H3saltren) have been successfully synthesized. Newly prepared compounds have been characterized by 1H-NMR, 13C-NMR, IR and UV–VIS spectroscopy techniques. The spectral studies confirmed the ligand coordinates the metal ion to form complex via the oxygen and nitroge...

Based-on the quasi-planar tetra-dentate Schiff-base ligand, a pair of manganese(III) Schiff-base enantiomers formulated as {[Mn(R,R-3-MeOSalcy)(H2O)(CH3OH)]ClO4}2 (1) and {[Mn(S,S-3-MeOSalcy)(H2O)(CH3OH)]ClO4}2 (2) (3-MeOSalcy = N,N′-(1,2-cyclohexanediylethylene)bis(3-methoxysalicylideneiminato)dianion) ...

An anti-tumor compound as N3-{phenyl [(4-pyridylcarbonyl) amino] methyl} weresynthesized and identified (NPPA). Fe (III), Co(II) and Pd(II) metal complexes of this ligand preparedby reaction of chloride salt of Fe (III), Co(II) and Pd(II) with NPPA in dry acetonitrile. Identification andCharacterization of the ligand was performed by FT-IR, 1H-NMR spectroscopy and elemental an...

2-(methylamino) pyridine (hmap) reacts with meli in thf and generates the lithium salt (limap). further reaction of [cu(tmeds)2][cucl2] (tmeda=tetramethylethylenediamine) with one equivalent of this ligand in thf leads to the formation of a yellow dimeric cu(i) complex, [cu(map)]2. analytical data, molecular weight, and magnetic susceptibility measurements, confirm the formula [cu(map)]2 .