In the present paper we describe a phase transfer of aqueous synthesized gold nanoparticles (AuNPs) from water to toluene using secondary amines: dioctylamine, didodecylamine, and dioctadecylamine. The effect of the hydrocarbon chain length and amount of amines on the transfer efficiency were investigated in the case of nanoparticles (NPs) with three different sizes: 5, 9, and 13 nm. Aqueous co...

The U.S. Environmental Protection Agency (EPA) implemented a program to identify tailpipe emissions of criteria and air-toxic contaminants from in-use, light-duty low-emission vehicles (LEVs). EPA recruited 25 LEVs in 2002 and measured emissions on a chassis dynamometer using the cold-start urban dynamometer driving schedule of the Federal Test Procedure. The emissions measured included regulat...

The design, calibration, and deployment of a buoy and gas-capture assembly for measuring bubbling gas flux in oceans and lakes are described. The assembly collects gas in a chamber while continuously measuring the position of the gas–water interface that forms as gas accumulates. Interface position is determined from the differential pressure between the chamber and ambient seawater. A spar buo...

Crude oil is not a specific single mineral substance. It is often called petroleum hydrocarbon because of its predominant make up of carbon and hydrogen, though it sometimes contains other elements1. There are many types of crude oil having widely different properties. Such variability are related to their behaviour and even degradation on spillage. Crude oil can however be divided into two: he...

Following a series of recent studies that demonstrated enhanced visible-light photocatalytic activities of TiO2 by annealing in reducing atmospheres, a systematic investigation was conducted, in which TiO2 nanoparticles were annealed in various controlled atmospheres with the estimated oxygen partial pressure being varied from 10 1 to 10 25 atm and presence of other species (Ar, H2, N2, vacuum ...

Almost three quarters of the hydrocarbon (HC) emissions emitted by an automobile in a typical drive-cycle are produced during the first three minutes of its operation called the coldstart period. In this paper, we propose a way to decrease cold start emissions. A Model-Based paradigm is used to aid the generation of an efficient controller. The controller is built around a mean value engine mod...

We synthesize impediments for evaluating effects to seabirds from open ocean hydrocarbon releases. Effects on seabirds from ship discharges, spills, and well blowouts often are poorly detected and monitored far from land. Regulatory regimes for ocean spills can result in monitoring efforts that are not entirely transparent. We illustrate how interdisciplinary technologies address deficits that ...

lurestan province is petroliferous area. the reserved oil are in ilam and sarvak  (cretaceous ) and kangan ( lower triassic ) and dalan (permian) formations. the lurestan area had high exploration activity but contribution of source rocks in hydrocarbon accumulations isn’t clear. in this paper essential elements and process of hydrocarbon accumulation are introduced. candidate  source  rocks ar...

Researchers devote to design catalytic systems with higher activity, selectivity, and stability ideally based on cheap and earth-abundant elements to reduce CO2 to value-added hydrocarbon fuels under mild conditions driven by visible light. This may offer profound inspirations on that. A bi-functional molecular iron catalyst designed could not only catalyze two-electron reduction from CO2 to CO...

There is growing interest in using seismic attenuation for reservoir characterization. We measure limestone samples in the laboratory to analyze attenuation and elastic moduli as a function of frequency from 3 Hz to ultrasonic. We observe that there is a positive correlation between bulk modulus dispersion and permeability. We also measure different modes of attenuation and find that the attenu...