Using grand canonical Monte Carlo simulation we show, for the first time, the influence of the carbon porosity and surface oxidation on the parameters of the Dubinin-Astakhov (DA) adsorption isotherm equation. We conclude that upon carbon surface oxidation, the adsorption decreases for all carbons studied. Moreover, the parameters of the DA model depend on the number of surface oxygen groups. T...

A lignocellulose/montmorillonite (LMT) nanocomposite was prepared as a reusable adsorbent for cobalt(II) ions, and characterized by nitrogen (N₂) adsorption/desorption isotherm, X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), Transmission Electron Microscopy (TEM), and Fourier Transform Infrared Spectroscopy (FTIR). LMT exhibited efficient adsorption of cobalt ions (Co(II)), and th...

soils around mining sites play a significant role in the transport and control of heavy metals in the environment. therefore, understanding the adsorption properties of soil is essential in solving pollution problems. the objective of this paper was to study zn(ii) adsorption onto sarcheshmeh copper mine soils. the adsorption isotherms of zn(ii) were studied. the langmuir isotherm indicated an ...

This investigation reveals the capability of Agave lechuguilla for trivalent and hexavalent chromium removal from aqueous solutions. Experimentation included pH profile, time dependence, adsorption capacity (K(F) and Q(L)), adsorption intensity (n and R(L)) and saturation capacity (q(s)) studies. Batch experiments were conducted at 22( composite function)C to characterize and model the adsorpti...

A low-cost activated carbon (XSBLAC) prepared from XanthocerasSorbifoliaBungehull via chemical activation was investigated to determine its adsorption and desorption properties for zinc(II) ions from aqueous solutions. XSBLAC was characterized based on its N₂-adsorption/desorption isotherm, EDX, XRD, SEM and FTIR results. An adsorption study was conducted in a series of experiments to optimize ...

introduction:thepowderedactivatedcarbontreatment(pact)hasbeenproposedasanalternativeinwastewatertreatmentandwastewaterbiomassprotectionagainsttoxicsubstances.thisstudyaimstoevaluatepactperformanceintreatingdyes,acidorange,andremazolbrilliantreactiveblue. methods:thisempirical-appliedresearchwascarriedoutinpilotscaleinwhichdifferentdyeremoval systems were tested:activatedsludge,pac,andthecombine...

We report an investigation of water adsorption in the hydrophobic metal-organic framework Al(OH)(1,4-naphthalenedicarboxylate) by means of molecular simulation. We show how simple molecular models allow us to reproduce the experimental isotherm, and how grand canonical Monte Carlo simulations can help elucidate the question of the thermodynamic nature of the adsorption transition, which turns o...

Removal of cesium from synthetic aqueous solution through adsorption on bentonite, under batch equilibrium experimental condition at different values of pH and four temperatures (303, 313, 323, 333 K) was investigated. For this propose the suitability of the Freundlich adsorption model for equilibrium data were investigated. The parameters in the adopted adsorption isotherm models were determin...

Sawdust is obtained from naturally and easily available which is biodegradable. The bio sorption capacity of the sawdust for hexavalent chromium was studied at different solution pH values (1.5-6), initial metal concentration (50450 mg/L), adsorbent dose (1-7 g/L). The maximum adsorption of Cr (VI) is obtained at pH 1.5, initial concentration 50 ppm and adsorbent dose 5 g/l. The adsorption of c...

Boron removal capacity of multi-walled carbon nanotubes (MWCNTs) modified with tartaric acid was investigated in this study. Modification of MWCNTs with tartaric acid was confirmed by Boehm surface chemistry method and fourier transform infra-red (FT-IR) spectroscopy. Experiments were performed to determine the adsorption isotherm and adsorption thermodynamic parameters of boron adsorption on t...