in this work, we report results of calculations based on the density functional theory of different species metal-ozone, containing mercury, silver and gold. the chosen species range from small molecules and large transition-metal containing ozone with mercury, silver and gold complexes. a comparative analysis of the description of the metal-oxygen bond obtained by different methodologies is pr...

We provide electrical circuit descriptions for bulk plasmons, single surface plasmons, and parallel-plate plasmons. Simple circuits can reproduce the exactly known frequency versus wave-vector dispersion relations for all these cases, with reasonable accuracy. The circuit paradigm directly provides a characteristic wave-impedance, Zo, that is rarely discussed in the context of plasmonics. The c...

in this study caulerpa racemosa has been characterized and used for the removal of cd(ii) and pb (ii) from aqueous solutions. the effect of ph, adsorbent dosage, contact time and temperature on adsorption process was studied in batch experiments. langmuir and freundlich models were applied to describe the biosorption isotherm of the metal ions by c. racemosa biomass. the adsorption data can be ...

this study proposes a method employing thermogravimetric analysis (tg) to predict pollutionlevels by heavy metals (cr, cu, ni, zn, pb, cd and hg) in port sediments close to urban and industrial sitesfrom bay of cádiz. for this purpose, the thermogravimetric results of 14 sediment samples were recorded andshowed two characteristic ranges of temperatures (w1 as weight loss, %: 200-650°c) vs. (w2 ...

slab method of analysis has been used for solving metal forming problems for a long time. however it has been restricted to plane strain and axisymmetric problems due to limitations in its formulations. in this paper a new formulation has been proposed so that it could be applied to three dimensional problems in metal forming. a parametric slab has been considered in this analysis and the force...

The visible (532 and 442 nm) and UV (325 nm) Raman spectra of bulk mixed metal oxides (metal molybdates and metal vanadates) were compared on the same spectrometer, for the first time, to allow examination of how varying the excitation energy from visible to UV affects the resulting Raman spectra. The quality of the Raman spectra was found to be a strong function of the absorption properties of...

This paper proposes a full adder with minimum power consumption and lowloss with a central frequency of 1550nm using plasmonic Metal-Insulator-Metal (MIM)waveguide structure and rectangular cavity resonator. This full adder operates based onXOR and AND logic gates. In this full adder, the resonant wave composition of the firstand second modes has been used and we have ob...

The presence of a metal nanoparticle (MNP) near a quantum dipole emitter, when a localized surface plasmon mode is excited via the resonant coupling with an excited quantum dipole, dramatically changes the relaxation dynamics: an exponential decay changes to step-like behavior. The main physical consequence of this relaxation process is that the emission, being largely determined by the MNP, co...

The optical properties of metallic nanoparticles (NPs) can be described with analytical models based on fundamental quantum mechanical principles, of which the Drude model constitutes the classical limit. Here, we examine the plasmonic properties of silver and gold nanospheres and dimers, with radii ranging from 10 to 1 nm, extending from the classically described regime to the quantum size reg...

In this paper, the use of a new technique to obtain transient sensor information is introduced and its usefulness to improve the selectivity of metal oxide gas sensors is discussed. The method is based on modulating the flow of the carrier gas that brings the species to be measured into the sensor chamber. In such a way, the analytes' concentration at the surface of the sensors is altered. As a...