In this study we address the problem of the response of a (electro)chemical oscillator towards chemical perturbations of different magnitudes. The chemical perturbation was achieved by addition of distinct amounts of trifluoromethanesulfonate (TFMSA), a rather stable and non-specifically adsorbing anion, and the system under investigation was the methanol electro-oxidation reaction under both s...

in the urine, and the kidney must have a considerable power of concentrating formate. The inhibition of the appearance of formate during the administration ofethanol is in accordance with Zatman's (1946) interpretation of the earlier experiments, namely, that a primary oxidation of methanol to formaldehyde through the agency of alcohol dehydrogenase is competitively inhibited by ethanol. More r...

A hybrid for the visible-light-driven photocatalytic reduction of CO2 using methanol as a reducing agent was developed by combining two different types of photocatalysts: a Ru(II) dinuclear complex (RuBLRu') used for CO2 reduction is adsorbed onto Ag-loaded TaON (Ag/TaON) for methanol oxidation. Isotope experiments clearly showed that this hybrid photocatalyst mainly produced HCOOH (TN = 41 for...

The problem of non-stationarity in experimentally recorded time-series is common in many (electro)chemical systems. Underlying this non-stationarity is the slow drift in some uncontrollable parameter, and it occurs in spite of the fact that all controllable parameters are kept constant. Particularly for electrochemical systems, some of us have recently suggested [J. Phys. Chem. C, 144, (2010), ...

a micro-channel heat exchanger reactor with different micro-baffle shapes has been studied numerically. governing equations were solved base on the finite volume method with fluent software. in upper section, oxidation reaction of methanol was occurred and in lower section, steam reforming of methanol was done. two sections were separated with solid part which played as heat exchanger and trans...

Monodispersed bimetallic PdAg nanoparticles can be fabricated through the emulsion-assisted ethylene glycol (EG) ternary system. Different compositions of bimetallic PdAg nanoparticles, Pd₈₀Ag₂₀, Pd₆₅Ag₃₅ and Pd₄₆Ag₅₄ can be obtained via adjusting the reaction parameters. For the formation process of the bimetallic PdAg nanoparticles, there have two-stage growth processes: firstly, nucleation a...

Methanotrophs in enrichment cultures grew and sustained atmospheric methane oxidation when supplied with methanol. If they were not supplied with methanol or formate, their atmospheric methane oxidation came to a halt, but it was restored within hours in response to methanol or formate. Indigenous forest soil methanotrophs were also dependent on a supply of methanol upon reduced methane access ...

The molecular structures and surface chemistry of mixed metal oxide heteropolyoxo vanadium tungstate (H(3+x)PW(12-x)V(x)O(40) with x = 0, 1, 2, and 3) Keggin nanoparticles (NPs), where vanadium is incorporated into the primary Keggin structure, and supported VO(x) on tungstophosphoric acid (TPA, H(3)PW(12)O(40)), where vanadium is present on the surface of the Keggin unit, were investigated wit...

Copper ion catalyzed carbon-carbon bond forming reaction of N-acyliminium ions with diaryl malonates was achieved with high enantioselectivity. The key intermediates in the method were 2-methoxy-3,4-didehydropiperidines, which were easily prepared through electrochemical oxidation of 1-(p-methoxybenzoyl)piperidine in methanol followed by the conversion of the oxidation product to didehydropiper...