The reduction of fossil CO2 emissions from key relevant industrial processes represents an important environmental challenge to be considered. To enable large-scale deployment low carbon technologies, a significant research and development effort is required optimize the capture systems. This work assesses various hybrid solvent-membrane configurations for post-combustion decarbonization coal-b...

Isolated five known iridoids glycosides (Scrophuloside A, Harpagoside B, 5-hydroxyloganin, 8-O-acetylharpagide and 6-O-methyl,1-glucopyranosyl catalpol), one phenyl ethanoid glycoside (Verbascoside) and a phenyl ethanol amine (2-(4-Chlorobenzyl amino) ethanol) compound from the methanolic extract of aerial parts of Scrophularia oxysepala using by high performance liquid chromatographyare based ...

The MnBr2 complex of N2,N6-bis-(di-tert-butyl-phosphan-yl)pyridine-2,6-di-amine (1·MnBr2) co-crystallizes with 5.69% of the monophosphine oxide analogue (1O·MnBr2) and two tetra-hydro-furan (THF) mol-ecules, namely [N2,N6-bis-(di-tert-butyl-phosphan-yl)pyridine-2,6-di-amine]-dibromido-manganese(II)-[bis-(di-tert-butyl-phosphan-yl)({6-[(di-tert-butyl-phosphan-yl)amino]-pyridin-2-yl}amino)-phosph...

A series of 1-(4-methylquinolin-2-yl)-4,6-diaryl-1H-pyrazolo[3,4-b]pyridin-3-amine derivatives was synthesized by the reaction of 3-cinnamoyl-4-hydroxy-6-methyl-2H-pyran-2-ones with 2-chloro-4,6-diphenylnicotinonitrile analogues in the presence of 2-hydrazino-4-methyl quinoline and ethanol. The newly synthesized compounds were characterized by IR, 1H NMR and mass spectral data. The synthetic se...

The polymerization of N-carboxyglycine anhydride has been used to identify potential inhibitors of protein synthesis and hence of cancers. Polymerization inhibition was observed wi th N-me thylbis(2.chloroethyl)amine HC1, busulfan, I ,9-dimethylsulfonyloxynonane, phenyl isocyanate, etc. (14), tris(2-chloroethyl)amine HC1 (7), and chiorambudil (G. E. Moos and J. B. Morrison, unpublished data). I...

A simple and straightforward method has been proposed for quantification of residual amine in cured epoxy resin. Non-bounded triethylenetetramine was extracted from epoxy polymer and determined via spectrophotometry using alizarin chromophore. Four solvents commonly used as food simulants, namely water, 95% ethanol, 10% ethanol and 3% acetic acid were examined. Released amine induces changes in...

The reaction of di-chlorido-tetra-kis-(dimethyl sulfoxide)-ruthen-ium(II) with N,N-bis[(pyridin-2-yl)meth-yl]methyl-amine aff-ords the title complex, [RuCl2(C13H15N3)(C2H6OS)]. The asymmetric unit contains a well-ordered complex mol-ecule. The N,N-bis-[(pyridin-2-yl)meth-yl]methyl-amine (bpma) ligand binds the cation through its two pyridyl N atoms and one aliphatic N atom in a facial manner. T...

The title dinuclear copper(II) complex [Cu2(C18H16Br2N2O4S2)2] was prepared by direct synthesis of a dianionic Schiff base derived from 5-bromo-salicyl-aldehyde and cyste-amine. The discrete mol-ecules lie across inversion centers and crystallize with two di-methyl-formamide (DMF) mol-ecules of crystallization. The unique CuII ion is four-coordinated by two tetra-dentate Schiff base ligands in ...

In the mononuclear title complex, [HgCl2(C20H21N3)], synthesized from the quinoline-derived Schiff base N (1),N (1)-diethyl-N (4)-(quinolin-2-yl-methyl-idene)benzene-1,4-di-amine (QMBD), the coordination geometry around the Hg(2+) atom is distorted tetra-hedral, comprising two Cl atoms [Hg-Cl = 2.3654 (19) and 2.4394 (18) Å] and two N-atom donors from the QMBD ligand, viz. one imine and quinoli...

In the title half-sandwich complex, [RuCl(η(6)-C(12)H(18))(C(10)H(9)N(3))]PF(6)·CH(2)Cl(2), the ruthenium(II) ion is four-coordinated by a chloro, a hexa-methyl-benzene and a bidentate N,N'-chelating di(pyridin-2-yl)amine ligand. In the crystal, the amino N-H group forms a hydrogen bond with the chloro ligand of a neighbouring complex, thus forming chains along the b axis. Weak inter-molecular ...