Mn-doped SrTiO(3.0), when synthesized free of impurities, is a paramagnetic insulator with interesting dielectric properties. Since delocalized charge carriers are known to promote ferromagnetism in a large number of systems via diverse mechanisms, we have looked for the possibility of any intrinsic, spontaneous magnetization by simultaneous doping of Mn ions and electrons into SrTiO3 via oxyge...

Recent advances in nanotechnology could facilitate the production of cheaper solar cells. This review describes synthetic routes to various nanostructured materials that are potentially useful in photovoltaic applications. We have focused on materials that are based on earth abundant elements and/or those that are held to have lower toxicity. Methods to synthesize binary chalcogenides with vari...

The development of ferromagnetism in Mn-doped Bi2Te3 is characterized through measurements on a series of single crystals with different Mn content. Scanning tunneling microscopy analysis shows that the Mn substitutes on the Bi sites, forming compounds of the type Bi2−xMnxTe3, and that the Mn substitutions are randomly distributed, not clustered. Mn doping first gives rise to local magnetic mom...

in this study, the effectiveness of kiwi shell was investigated to reduce the mobility of lead and cadmium in clay soil in different intervals. for this purpose a clay soil sample was contaminated with lead and cadmium in distinct dishes with 10 and 600 ppm concentrations respectively and mixed with 5% kiwi shell. samples were placed in incubator, and then sampling of soil in incubator was perf...

For colloidal semiconductor nanocrystals (NCs), shape control and doping as two widely applied strategies are crucial for enhancing and manipulating their functional properties. Here we report a facile and green synthetic approach for high-quality colloidal Mn doped ZnO NCs with simultaneous control over composition, shape and optical properties. Specifically, the shape of doped ZnO NCs can be ...

Doped ZnS quantum dots (QDs) have a longer dopant emission lifetime and potentially lower cytotoxicity compared to other doped QDs. The liver is the key organ for clearance and detoxification of xenobiotics by phagocytosis and metabolism. The present study was designed to synthesize and evaluate the hepatotoxicity of Mn-doped ZnS QDs and their polyethylene glycol-coated counterparts (1 mg/kg an...

In situ grown nickel sulfide and cobalt sulfide hierarchical nanospheres on F-doped SnO2 (FTO) substrates exhibited comparable catalytic activities to sputtering Pt on the counter electrodes for dye-sensitized solar cells (DSSCs). The fresh cells with the nickel sulfide and cobalt sulfide on the counter electrodes could reach power conversion efficiencies of 6.81% and 6.59% respectively, approa...

A general approach for the synthesis of manganese-doped II-VI and III-V nanowires based on metal nanocluster-catalyzed chemical vapor deposition has been developed. High-resolution transmission electron microscopy and energy-dispersive X-ray spectroscopy studies of Mn-doped CdS, ZnS, and GaN nanowires demonstrate that the nanowires are single-crystal structures and homogeneously doped with cont...

In this study, ZIF-8 MOF nanocrystals were synthesized and post-synthetically modified by applying different cation exchange strategies. Addition of cadmium nitrate in either methanol or DMF followed magnetic stirring gentle heating led to the incorporation a small amount Cd (II) ions into crystal structure most cases, as clearly demonstrated several characterization techniques including PXRD, ...

OF DOCTORAL DISSERTATION HELSINKI UNIVERSITY OF TECHNLOGY P.O. BOX 1000, FI-02015 TKK http://www.tkk.fi Author Heikki Holmberg Name of the dissertation Spin-dependent transport in Mn Doped GaAs and GaN diodes Manuscript submitted 16.11.2007 Manuscript revised 4.2.2008 Date of the defence 14.3.2008 Monograph Article dissertation (summary + original articles) Faculty Faculty of Electronics, Commu...