نتایج جستجو برای: mofs
تعداد نتایج: 2266 فیلتر نتایج به سال:
چارچوبهای آلی فلزی(mofs)به عنوان نوع جدیدی از مواد بلوری متخلل با کاربردهای متعددی از جمله:جداسازی و ذخیره سازی گاز ،تبادل یونی،سنسورها،کاتالیست ،مواد شب تاب و فلورسنت و مواد نوری. همچنین چهارچوبهای آلی فلزی (mofs)به عنوان پلیمرهای کورئودینه شناخته می شود که از گره های فلزی متصل شده توسط پیوند های آلی تشکیل شده است درچند دهه گذشته(mofs)توجه زیادی به علت خواص خاص خود مانند:مساحت زیاد همراه تبل...
Metal-organic frameworks (MOFs) are a class of hybrid materials with unique optical and electronic properties arising from rational self-assembly of the organic linkers and metal ions/clusters, yielding myriads of possible structural motifs. The combination of order and chemical tunability, coupled with good environmental stability of MOFs, are prompting many research groups to explore the poss...
The synthetically tunable properties and intrinsic porosity of conductive metal-organic frameworks (MOFs) make them promising materials for transducing selective interactions with gaseous analytes in an electrically addressable platform. Consequently, conductive MOFs are valuable functional materials with high potential utility in chemical detection. The implementation of these materials, howev...
The field of coordination polymers and metal–organic frameworks (MOFs) has evolved over a period of approximately 25 years to a stage where it is one of the most widely investigated areas of materials chemistry. The field has impacted many areas of science including commercial applications from gas storage agents to new investigations as drug-delivery vehicles [1]. Coordination polymers and MOF...
While glassy materials can be made from virtually every class of liquid (metallic, molecular, covalent, and ionic), to date, formation of glasses in which structural units impart porosity on the nanoscopic level remains undeveloped. In view of the well-established porosity of metal-organic frameworks (MOFs) and the flexibility of their design, we have sought to combine their formation principle...
Metal-organic frameworks (MOFs) have been considered as highly promising materials for adsorption-based CO2 separations. The number of synthesized MOFs has been increasing very rapidly. High-throughput molecular simulations are very useful to screen large numbers of MOFs in order to identify the most promising adsorbents prior to extensive experimental studies. Results of molecular simulations ...
We performed ab initio calculations of the elastic constants of five flexible metal-organic frameworks (MOFs): MIL-53(Al), MIL-53(Ga), MIL-47, and the square and lozenge structures of DMOF-1. Tensorial analysis of the elastic constants reveals a highly anisotropic elastic behavior, some deformation directions exhibiting very low Young's modulus and shear modulus. This anisotropy can reach a 400...
The properties of metal-organic frameworks (MOFs) can be tuned by postsynthetic modification (PSM) to introduce specific functionalities after their synthesis. Typically, PSM is carried out on pendant functional groups or through metal/ligand exchange, preserving the structure of the MOF. We report herein the bromination of integral alkyne units in a pair of Zr(4+) and Hf(4+) MOFs, which procee...
Electroreduction of oxoanions affords hydroxide equivalents that induce selective deposition of crystalline metal-organic frameworks (MOFs) on conductive surfaces. The method is illustrated by cathodic electrodeposition of Zn(4)O(BDC)(3) (MOF-5; BDC = 1,4-benzenedicarboxylate), which is deposited at room temperature in only 15 min under cathodic potential. Although many crystalline phases are k...
A new class of metal-organic frameworks (MOFs) has been synthesized by ligand-functionalization strategy. Systematic studies of their adsorption properties were performed at low and high pressure. Importantly, when fluorine was introduced into the framework via the functionalization, both the framework stabilities and adsorption capacities towards H2/CO2 were enhanced significantly. This conseq...
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