To elucidate plant mechanisms involved in molybdenum (Mo) sequestration and tolerance, Brassica spp. seedlings were supplied with molybdate, and the effects on plant physiology, morphology, and biochemistry were analyzed. When supplied with (colorless) molybdate Indian mustard (Brassica juncea) seedlings accumulated water-soluble blue crystals in their peripheral cell layers. Energy dispersive ...

A molybdenum-reducing bacterium from Antarctica has been isolated. The bacterium converts sodium molybdate or Mo⁶⁺ to molybdenum blue (Mo-blue). Electron donors such as glucose, sucrose, fructose, and lactose supported molybdate reduction. Ammonium sulphate was the best nitrogen source for molybdate reduction. Optimal conditions for molybdate reduction were between 30 and 50 mM molybdate, betwe...

A simple and sensitive suppressed ion chromatography (IC) method with conductivity detection for the determination of molybdate in environmental water is proposed. Molybdate in highly saline water was extracted and preconcentrated. Preconcentration was accomplished by using a chelating resin using a chelating resin immobilized with carboxymethylated polyethylenimine (Presep(®) PolyChelate). Thi...

The great instability of creatine phosphate (Fiske & Subbarow, 1929), acetyl phosphate (Lipmann & Tuttle, 1944) and 1:3-diphosphoglyceric acid (Negelein & Bromel, 1939) in solutions containing molybdate has been known almost as long as these compounds themselves. It could not fail to attract the attention of the analyst who used a method of phosphate estimation ofthe Briggs (1922) or Fiske & Su...

Sphere-like cadmium molybdate (CdMoO4) nanostructures have been synthesized by a large scale and simple sonochemical method by using Cd(Sal)2 (Sal=salicylidene) and Na2MoO4.2H2O for the first time. The effects of sonochemical irradiation time, sonochemical power, temperature, solvent, surfactant and cadmium source were considered to obtain a controlled shape. The as-prepared nanostructured cadm...

One-, two- and three-dimensional nanostructures of copper molybdenum oxide hydroxide were successfully constructed by a simple approach through a pH-dependent dimensional transformation of ammonium copper molybdate. Thin nanoplates of copper molybdate, which were obtained by sintering the two-dimensional nanobelts of copper molybdenum oxide hydroxide, exhibited remarkably high reversible lithiu...

A facile, efficient, simple, environmentally safe, regioselective, controllable and economical method for the oxybromination of aromatic compounds using sodium molybdate in presence of mineral acids and H2O2. The use of sodium molybdate as catalyst accelerates the rate of reaction in presence of mineral acids and hydrogen peroxide.

in this research, a new technetium-99m generator has been developed with addition of cerium oxide to alumina column.  the adsorption behaviors of 99mo in the form of molybdate and 99mtc in the form of pertechnetate on ceo2/al2o3 was investigated and showed that the adsorption capacity of molybdate on this generator is higher than usual generator using al2o3. ceric ions were selected as an addit...

A PVC-based membrane containing cerium phosphate was developed. Unlike the cerium phosphate itself that acts as a cation exchanger, the membrane exhibited anion-exchange properties. Therefore, the utility of this compound as a sensory element for detection of molybdate ions was pursued. The response of molybdate selective electrode based on this membrane was perfectly linear in the concentr...

The decomposition of ammonium heptamolybdate was investigated by in situ XAFS and in situ XRD to elucidate the influence of different atmospheres on the products formed the formation of different decomposition products and various intermediates is described in detail.