Perovskite LaFeO3/montmorillonite nanocomposites (LaFeO3/MMT) have been successfully prepared via assembling LaFeO3 nanoparticles on the surface of montmorillonite with citric acid assisted sol-gel method. The results indicated that the uniform LaFeO3 nanoparticles were densely deposited onto the surface of montmorillonite, mainly ranging in diameter from 10 nm to 15 nm. The photocatalytic acti...

A b s t r a c t S u r f a c e area determinations were made on a montmorillonite with various cations emplaced on the exchangeable sites, utilizing nitrogen and carbon dioxide as adsorbates at 77~ and 195~ respectively, in a dynamic system. From the fraction of a Mississippi montmorillonite less than about 1/x in size, samples were prepared by replacing the original exchangeable cations with Li...

Changes in the structure of phyllosilicate microparticles submicron fractions polymineral clay with an average size 290 nm, as well changes positions impurity ions transition metals crystal lattice, were studied by X-ray diffraction analysis, Fourier transform infrared spectroscopy, and high-resolution electron paramagnetic resonance spectroscopy. The main composition included clinochlore, mont...

Polyvinyl chloride (PVC)/organic-montmorillonite composites were prepared by melt intercalation. Their structures and properties were investigated with X-ray diffraction (XRD), differential scanning calorimetry (DSC) and mechanical testing. The results showed that PVC chains could be intercalated into the gallery of organically modified montmorillonite to form exfoliated PVC/organic-montmorillo...

Zinc sorption to hydrous manganese oxide (HMO)-coated clay was investigated macroscopically, kinetically, and spectroscopically. Adsorption edges and isotherms revealed that the affinity and capacity of the HMO-coated montmorillonite was greater than that of montmorillonite, and when normalized to the oxide present, the coatings behaved similarly to the discrete Mn oxide. Over two pH conditions...

This paper first deals with the screening and optimization of Fe(III)-based adsorbents for arsenic adsorption from 0.2 to 16 ppm test solutions of arsenite/arsenate. The best adsorption capacity has been reported on alpha-FeO(OH) on an adsorbent weight basis. Better results were found on intercalated Fe-montmorillonites for arsenite adsorption below the equilibrium dissolved As concentration of...

The montmorillonite sample from Heping, China had been studied by chemical analysis, XRD, IR, AFM and MAS NMR. The results showed that acid concentration had much influence on surface structure of montmorillonite. When the acid concentration reached 2M, the Q3Si structure in silica-oxygen tetrahedron recombined, some Q3Si structure in montmorillonite transformed to distortion Q3Si structure and...

Chitosan/montmorillonite nanocomposite films were prepared by the solvent evaporation method to immobilize drug ibuprofen (IBU) and delay its release in a medium that simulates environment of gastrointestinal tract. The effects montmorillonite, at different mass proportions (10, 20, 50%), on morphological physical properties studied. samples characterized X-ray diffraction (XRD), Infrared Spect...

It has been known for some time that when a gel of montmorillonite is freeze-dried the residual clay retains the volume and shape of the gel, and forms a skeleton of low density and some rigidity. Because there is no apparent change in the gel structure during freeze-drying, the dry residues have been studied in the past in an effort to determine the structure of the gels. However, X-ray diffra...