Montmorillonite (MMT) clay mineral is widely used as filler for several organic coatings. Its activity is increased by exfoliation via chemical modification to produce nanomaterials. In the present work, the modification of MMT to form nanogel composites is proposed to increase the dispersion of MMT into epoxy matrices used to fill cracks and holes produced by the curing exotherms of epoxy resi...

Well-defined homo glycopolymer/montmorillonite (MMT) nanocomposite (gly1) was prepared successfully by the “grafting from” technique from the modified surface of MMT via surface initiated atom transfer radical polymerization (SI-ATRP) of 3-O-methacryloyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose (gly) in the presence of Cu(I)Br/bipyridyl at 90 ̊C in xylene. Well-defined diblock copolymers (g...

Layered double hydroxides (LDHs), luminescent π-conjugated anionic polymer and montmorillonite (MMT) were orderly assembled into luminescent multilayer films via layer-by-layer self-assembly method. The electronic microenvironment (EME), the structure of which is like a traditional capacitor, can be constructed by exfoliated LDHs or MMT nanosheets. In addition, the rigid inorganic laminated con...

Inorganic nanosized silicate nanoplatelets were incorporated into biodegradable poly(L-lactic acid) (PLLA) for the purpose of tailoring mechanical stiffness of PLLA porous scaffold systems. Increasing the nucleation density around the foreign body surfaces, the montmorillonite (MMT) nanoplatelets modified with dimethyl dihydrogenated tallow ammonium cations decreased the glass transition temper...

Copolymers consisting of methyl methacrylate (MMA) and methacrylic acid (MAA) and their layered silicate nanocomposites were electrospun to form fibers with diameters in the sub-micron range. The presence of MAA increased the glass transition temperature and thermal stability of the copolymers through formation of anhydrides upon heating. Dispersion of layered silicates within the nanocomposite...

The treatment of catechol via biocatalysis and adsorption with a commercial laccase immobilized on polyacrylonitrile/montmorillonite/graphene oxide (PAN/MMT/GO) composite nanofibers was evaluated with a homemade nanofibrous membrane reactor. The properties in this process of the immobilized laccase on PAN, PAN/MMT as well as PAN/MMT/GO with different weight ratios of MMT and GO were investigate...

The non-biodegradable and non-renewable nature of plastic packaging has led to a renewed interest in packaging materials based on bio-nanocomposites (biopolymer matrix reinforced with nanoparticles such as layered silicates). Bio-nanocomposite films based on soy protein isolate (SPI) and montmorillonite (MMT) were prepared using melt extrusion. Effects of the pH of film forming solution, MMT co...

The nonbiodegradable and nonrenewable nature of plastic packaging has led to a renewed interest in packaging materials based on bio-nanocomposites (biopolymer matrix reinforced with nanoparticles such as layered silicates). Bio-nanocomposite films based on soy protein isolate (SPI) and modified montmorillonite (MMT) were prepared using melt extrusion. The effect of different type (Cloisite 20A ...

We describe the influence of calcium copper titanate (CCTO), and montmorillonite (MMT) on the thermo-mechanical and dielectric properties of poly(methyl methacrylate) PMMA-based composites prepared by an in-situ, thermally activated, radical polymerization for multifunctional structural capacitor applications. MMT was used for its ability to disperse and suspend the CCTO particles through the g...

Polyvinyl alcohol (PVA) / starch (S) /Carboxy methyl cellulose (CMC) / Montmorillonite (MMT) bionanocomposite films were prepared from PVA, MMT, CMC and soluble starch aqueous suspensions by casting method in the presence of a plasticizer that contained glycerol. The kinetics of thermal degradation of PVA/S/CMC/MMT blends was investigated by thermogravimetry (TGA) and derivative thermogravimetr...