The difficulty of measuring gross N2O production and consumption in soil impedes our ability to predict N2O dynamics across the soil-atmosphere interface. Our study aimed to disentangle these processes by comparing measurements from gas-flow soil core (GFSC) and 15N2O pool dilution (15N2OPD) methods. GFSC directly measures soil N2O and N2 fluxes, with their sum as the gross N2O production, wher...

The analysis of the four main isotopic N2O species (NNO, NNO, NNO, NNO) and especially the intramolecular distribution of N (“site preference”, SP) has been suggested as a tool to distinguish source processes and to help constrain the global N2O budget. However, current studies suffer from limited spatial and temporal resolution capabilities due to the combination of discrete flask sampling wit...

The free-energy profile for N2O in a hydrated 1,2-dimyristoylphosphatidylcholine (DMPC) phospholipid bilayer is calculated. The N2O molecule is preferentially concentrated in the tail region of the DMPC lipid and there is no free-energy barrier for the diffusion of N2O from an aqueous environment into the lipid. Although the dipole moment of N2O is rather small, our calculation indicates that t...

Nitrous oxide (N2O) is an important and strong greenhouse gas in the atmosphere and part of a feed-back loop with climate. N2O is produced by microbes during nitrification and denitrification in terrestrial and aquatic ecosystems. The main sinks for N2O are turnover by denitrification and photolysis and photo-oxidation in the stratosphere. The position of the isotope N in the linear N=N=O molec...

Ammonia-oxidizing microorganisms are an important source of the greenhouse gas nitrous oxide (N2O) in aquatic environments. Identifying the impact of pH on N2O production by ammonia oxidizers is key to understanding how aquatic greenhouse gas fluxes will respond to naturally occurring pH changes, as well as acidification driven by anthropogenic CO2. We assessed N2O production rates and formatio...

Nitrification inhibitors may be potential management strategy to reduce N2O emissions in irrigated rice (Oryza sativa L.). A field experiment was conducted to evaluate chemically synthesized as well as locally available neem plant products on N2O emissions, from an irrigated rice at New Delhi, India. Emission of nitrous oxide (N2O) was monitored during 70 days by closed chamber method in rice (...

The continuous increase of the greenhouse gas nitrous oxide (N2O) in the atmosphere due to increasing anthropogenic nitrogen input in agriculture has become a global concern. In recent years, identification of the microbial assemblages responsible for soil N2O production has substantially advanced with the development of molecular technologies and the discoveries of novel functional guilds and ...

Nitrogen (N) deposition has increased significantly globally since the industrial revolution. Previous studies on the response of gaseous emissions to N deposition have shown controversial results, pointing to the system-specific effect of N addition. Here we conducted an N addition experiment in a temperate natural forest in northeastern China to test how potential changes in N deposition alte...

Nitrous oxide (N2O) has a global warming potential that is 300 times that of carbon dioxide on a 100-y timescale, and is of major importance for stratospheric ozone depletion. The climate sensitivity of N2O emissions is poorly known, which makes it difficult to project how changing fertilizer use and climate will impact radiative forcing and the ozone layer. Analysis of 6 y of hourly N2O mixing...

[1] We used the trace gas model DayCent to simulate emissions of nitrous oxide (N2O) from a urine-affected pasture in New Zealand. The data set for this site contained yearround daily emissions of nitrification-N2O (N2Onit) and denitrification-N2O (N2Oden), meteorological data, soil moisture, and at least weekly data on soil ammonium (NH4 ) and nitrate (NO3 ) content. Evapotranspiration, soil t...