The effect of temperature in the range of 0–150 8C was studied for homoionic montmorillonite clays with Na and Csqq compensating ions in low hydration states. Both static and dynamic information concerning the interlayer ions and water moleculeswas obtained by Monte Carlo and molecular dynamics. Principal structural changes were limited to the water phase, markeddifference was o...

Surfaces of Wyoming SWy-2-Na-montmorillonite were modified using ultrasonic and hydrothermal methods through the intercalation and adsorption of the cationic surfactant octadecyltrimethylammonium bromide (ODTMA). Changes in the surfaces and structure were characterized using X-ray diffraction (XRD), thermal analysis (TG), and electron microscopy. The ultrasonic preparation method results in a h...

A polycarbonate-based nanohybrid has been created containing 1 wt% of Bentone 2010, an organically modified montmorillonite. A micro-section on the nanohybrid obtained using focused ion beam (FIB) and field emission scanning electron microscopy (FESEM) was employed to observe the orientation of the nanoclay inside a polycarbonate (PC) matrix in the cross-section FIB-milled face. A micro-scratch...

-The conditions under which an exchanger phase will behave as an ideal mixture are established from thermodynamic principles. It is shown that, if a stoichiometric cation-exchange reaction is reversible, the exchanger phase will exhibit ideal behavior if the Vanselow selectivity coefficient is independent of the exchanger composition. This criterion is applied to some recently published data fo...

In this work, the influence of composition and cold-drawing on nanoand micro-scale morphology and tensile mechanical properties of PE/organoclay nanocomposite fibers was investigated. Nanocomposites were prepared by melt compounding in a twin-screw extruder, using a maleic anhydride grafted linear low density polyethylene (LLDPE–g–MA) and an organomodified montmorillonite (Dellite 67G) at three...

Polymer nanocomposites are new classes of composite materials derived from nanoparticles with at least one dimension in the nanometric range. Polypropylene nanocomposites have attracted a considerable interest due to its most widely used and fastest growing classes of thermoplastic polymer with low cost and low density. However, a problem associated with polypropylene is its dyeability. There h...

Nature is full of various nanomaterials and nanostructures that have inspired helped human life civilization in the advancement science technology. Among these materials are clays, which abundantly found rocks earth structures. The mineral montmorillonite, known as a clay nanoparticle, major phase bentonite. This nanoclay, with thickness about 10 angstroms, includes unique properties such expan...

An aluminous montmorillonite has been synthesized at hydrothermal conditions (623 K, 120 MPa) and compared to the natural Na-exchanged Wyoming montmorillonite (Na-SWy2). The synthetic product is characterized by a high cation exchange capacity (83 meq/100g) and ethylene glycol specific surface area (764 m 2 /g) similar to Na-SWy2 but with a higher purity with one crystalline phase. Compacted sm...