نتایج جستجو برای: nano ceria

تعداد نتایج: 52616  

2018
Francielli S Genier Maximilian Bizanek Thomas J Webster Amit K Roy

Conditions of cellular stress are often the cause of cell death or dysfunction. Sustained cell stress can lead to several health complications, such as extensive inflammatory responses, tumor growth, and necrosis. To prevent disease and protect human tissue during these conditions and to avoid medication side effects, nanomaterials with unique characteristics have been applied to biological sys...

2016
X. Wang Raymond J. Gorte J. P. Wagner

The mechanism responsible for the irreversible deactivation of ceria-supported precious metals for the watergas-shift reaction has been investigated through accelerated aging tests. It is shown that deactivation of Pd/ ceria occurs more rapidly at 673 K compared to 523 K when operating with an integral reactor in 25 torr each of CO and H2O. By heating a fresh catalyst in H2, H2O, CO, or CO2, it...

2003
Qi Fu Svetlana Kudriavtseva Howard Saltsburg Maria Flytzani-Stephanopoulos

Nanostructured Au–ceria is a promising new catalyst for low-temperature water-gas shift (LTS). Preparation, characterization, and catalytic properties of this material are reported in this paper. Gold–ceria was prepared by deposition–precipitation (DP), coprecipitation (CP), and gelation methods. The gold loading was varied between 1 and 8.3 at.%, while lanthanum used as a dopant in ceria, was ...

Journal: :Science 2013
Matteo Cargnello Vicky V T Doan-Nguyen Thomas R Gordon Rosa E Diaz Eric A Stach Raymond J Gorte Paolo Fornasiero Christopher B Murray

Interactions between ceria (CeO2) and supported metals greatly enhance rates for a number of important reactions. However, direct relationships between structure and function in these catalysts have been difficult to extract because the samples studied either were heterogeneous or were model systems dissimilar to working catalysts. We report rate measurements on samples in which the length of t...

2008
Rui Si Maria Flytzani-Stephanopoulos

The water–gas shift (WGS) reaction (CO+H2OQCO2+H2) plays an important role in fuel processing for polymer electrolyte membrane (PEM) fuel-cell applications. The hydrogen in the reformate gas is upgraded by removal of the carbon monoxide, which is a strong poison of the anode catalysts in current PEM fuel cells. Active shift catalysts that are also stable under the operating conditions of practi...

Journal: :The journal of physical chemistry. B 2006
Giulio Deganello Francesco Giannici Antonino Martorana Giuseppe Pantaleo Antonio Prestianni Antonella Balerna Leonarda F Liotta Alessandro Longo

The catalyst Pt(1 wt %)/Ce(0.6)Zr(0.4)O(2) is studied by CO-temperature programmed reduction (CO-TPR), isothermal oxygen storage complete capacity (OSCC), X-ray absorption spectroscopy (XAS) at the Pt L(III) edge, and in situ X-ray diffraction (in situ XRD), with the aim of elucidating the role of supported metal in CO oxidation by ceria-based three-way catalysts (TWC). The redox behavior of Pt...

Journal: :Angewandte Chemie 2012
Chi Kyung Kim Taeho Kim In-Young Choi Min Soh Dohoung Kim Young-Ju Kim Hyunduk Jang Hye-Sung Yang Jun Yup Kim Hong-Kyun Park Seung Pyo Park Sangseung Park Taekyung Yu Byung-Woo Yoon Seung-Hoon Lee Taeghwan Hyeon

Uniform 3 nm-sized ceria nanoparticles can protect against ischemic stroke by scavenging reactive oxygen species (ROS) and reducing apoptosis. PEGylated ceria nanoparticles showed protective effects against ROS-induced cell death in vitro. Optimal doses of ceria nanoparticles reduced infarct volumes and the rate of ischemic cell death in vivo.

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