The optical properties and charge trapping phenomena observed on oxide nanocrystal ensembles can be strongly influenced by the presence of nanocrystal interfaces. MgO powders represent a convenient system to study these effects due to the well-defined shape and controllable size distributions of MgO nanocrystals. The spectroscopic properties of nanocrystal interfaces are investigated by monitor...

Nanocrystalline magnesium ferrite is synthesized by high-energy ball milling. The formation of nanocrystalline ferrite phase is observed after 3 h of milling and its content increases with milling time. The structural and microstructural evolution of the nanophase have been studied by X-ray powder diffraction and the Rietveld method. After 3 h of milling, ferrite phase (mixed spinel) nucleates ...

Sintering of powders is a common means of producing bulk materials when melt casting is impossible or does not achieve a desired microstructure, and has long been pursued for nanocrystalline materials in particular. Acceleration of sintering is desirable to lower processing temperatures and times, and thus to limit undesirable microstructure evolution. Here we show that markedly enhanced sinter...

The raw materials constituting the Portland cement are mainly lime, silica, alumina and iron oxide. During the manufacturing process, a glassy quasicrystalline clinker is formed which is ground, normally with addition of 1-3 wt% of CaSCU in the cement powder. This powder has four major constituents: 3 CaO"SiO2 (in cement chemists' notation C3S), 2 CaOSiO2 (C2S), 3 CaOAl2O3 (C3A) and 4 GaOAl2O3F...

The first solvent-free crystal structure of PCBM, an organic semiconductor widely used in solvent-free nanocrystalline films in plastic solar cells, is reported and its relevance to structure-property relationships discussed. The PCBM structure, obtained from o-dichlorobenzene solvates by solvent abstraction, was solved using powder diffraction, demonstrating this possibility for functionalized...

A simple and convenient one-step method for synthesis of acridines and their derivatives from condensation of aromatic aldehydes, cyclic diketones, and aryl amines using Cu-doped ZnO nanocrystalline powder as a catalyst is reported. The present protocol provides several advantages such as good yields, short reaction time, easy workup, and simplicity in operation.

B. Ahn*, S. R. Nutt 1. Department of Chemical Engineering and Materials Science, University of Southern California, Los Angeles, CA, 90089-0241, USA *[email protected] Abstract: Al–Mg alloy powder was mechanically milled in liquid N2 (cryomilling) to produce thermally stable powder with nanocrystalline (NC) microstructure for the manufacture of highstrength alloys. A multi-scale microstructure w...

Ball milling has been shown to produce nanostructures in metal powders through severe repetitive deformation. Ball milling at cryogenic temperatures (cryomilling) is more effective in this capacity due to the low temperature by slowing recovery and minimizing diffusion distances between different components. Nanostructured metals are of interest because of their unique physical and mechanical p...