The reaction of the hydrazone, 2-methoxy-6-(pyridin-2-yl-hydrazonomethyl) phenol (LH) with lanthanide(iii) nitrate salts in the presence of excess triethylamine afforded the heptanuclear Ln(iii) complexes: [Gd7(L)6(μ3-OH)8(NO3)4(H2O)]·(NO3)3·8CH3CN·H2O (), [Tb7(L)6(μ3-OH)8(NO3)4]·(NO3)3·9CH3CN·2CH3OH·3H2O (), [Dy7(L)6(μ3-OH)8(NO3)4(H2O)]·(NO3)3·7CH3CN·3H2O (), [Ho7(L)6(μ3-OH)8(NO3)4]·(NO3)3·11C...

We investigated rice husk as the sole carbon source as well as biofilm carrier in the biological denitrification of wastewater in up-flow laboratory reactors. Fast startup of the reactor and high nitrate removal efficiency was observed. The highest denitrification rate (about 0.096kg/m·d) was achieved when flow rate and nitrate concentration were 41.4L/d and 25.0mg/L, respectively. Flow rate an...

Nutrient addition has been proved to be an effective strategy to enhance oil biodegradation in marine shorelines. To determine the optimal range of nutrient concentrations in the bioremediation of oil-polluted beaches, nitrate was added to the simulated shoreline models in the initial concentration of 1, 5 and 10 mg/L. Whenever the NO3-N concentration declined to 70% of its original value, addi...

nitrogen as one of the important nutrients of microalgae has significant affect on the growth and nutrition value of the algae if the changes. in present study the growth and fatty acids content of the different concentration of nitrate (0, 0.62, 1.25, 2.5 and 5 mm from no3) was studied during a 12 day cultivation period of haematococcus sp. and desmodesmus cunaetus. at 22 °c in laboratory cond...

high quantity of chemical fertilizer use in farms to increase production but low efficiency irrigation leaches part of nitrate and follows groundwater pollution. in this research, extra water below root zone as deep percolation collected with point drains which installed interface of natural drainage zone and agricultural soil in university of tehran research farms. then, concentration of nitra...

Nitrate (NO3) profiles in semiarid unsaturated zones archive land use change (LUC) impacts on nitrogen (N) cycling with implications for agricultural N management and groundwater quality. This study quantified LUC impacts on NO3 inventories and fluxes by measuring NO3 profiles beneath natural and rainfed (nonirrigated) agricultural ecosystems in the southern High Plains (SHP). Inventories of NO...

The paper describes the design of a finite state automaton which forms the kernel of an Intelligent Decision Support System that has been implemented and integrated into the existing supervisory control and data acquisition system at a medium scale municipal Wastewater Treatment Plant. The system provides real-time support and advice to the operators and the manager of the plant for a wide rang...

denitrification of high- nitrate high- salinity wastewater is difficult due to plasmolysis and inactivation of denitrifiers at high salinity conditions. in this study, the effects of salinity and empty bed contact time (ebct) on simultaneous heterotrophic and sulfur based autotrophic denitrification of synthetic wastewater were evaluated in an up flow packed bed reactor .the reactor was filled ...